Rotational Quenching Rate Coefficients For H_2 In Collisionswith H_2 From 2 To 10,000 K

T.-G. Lee; N. Balakrishnan; R. C. Forrey; P. C. Stancil; G. Shaw; D. R. Schultz; G. J. Ferland

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Rotational Quenching Rate Coefficients For H_2 In Collisionswith H_2 From 2 To 10,000 K

机译：H_2与H_2碰撞2到10,000 K时H_2的旋转淬火速率系数

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Rate coefficients for rotational transitions in H_2 induced by H_2 impact are presented. Extensive quantum mechanical coupled-channel calculations based on a recently published (H_2)_2 potential energy surface were performed. The potential energy surface used here has been demonstrated to be more reliable than surfaces used in previous work. Rotational transition cross sections with initial levels of J ≤ 8 were computed for collision energies ranging between 10~(-4) and 2.5 eV, and the corresponding rate coefficients were calculated for the temperature range 2 ≤ T ≤ 10,000 K. In general, agreement with earlier calculations, which were limited to 100-6000 K, is good, although discrepancies are found at the lowest and highest temperatures. Low-density-limit cooling functions due to para- and ortho-H_2 collisions are obtained from the collisional rate coefficients. Implications of the new results for nonthermal H_2 rotational distributions in molecular regions are also investigated.

机译：提出了由H_2冲击引起的H_2旋转跃迁的速率系数。基于最近发布的（H_2）_2势能面进行了广泛的量子力学耦合通道计算。已经证明，此处使用的势能表面比以前的工作中使用的表面更可靠。计算碰撞能量在10〜（-4）和2.5 eV之间的初始能级J≤8的旋转过渡截面，并在2≤T≤10,000 K的温度范围内计算出相应的速率系数。尽管在最低和最高温度下发现了差异，但采用较早的计算（限于100-6000 K）还是不错的。从碰撞率系数中获得了由于对位和邻位H_2碰撞引起的低密度极限冷却函数。还研究了新结果对分子区域中非热H_2旋转分布的影响。

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《The Astrophysical journal》 |2008年第2apart1期|1105-1111|共7页
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T.-G. Lee; N. Balakrishnan; R. C. Forrey; P. C. Stancil; G. Shaw; D. R. Schultz; G. J. Ferland;
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1. Rotational Quenching Rate Coefficients For H_2 In Collisionswith H_2 From 2 To 10,000 K [J] . T.-G. Lee, N. Balakrishnan, R. C. Forrey, The Astrophysical journal . 2008,第2apart1期

机译：H_2在2至10,000 K的碰撞中H_2的旋转淬火速率系数
2. State-to-state and total rotational energy transfer rate constants for N(B~2#SIGMA#~+, v=0,N)+H_2, CN(X~2#SIGMA#~+,v=2,N)+H_2, D_2, and CN(X~2#SIGMA#~+,v=3,N)+NO [J] . Sophie M. D. Brunet, Jingzhong Guo, Tucker Carrington, The Journal of Chemical Physics . 2002,第9期

机译：N（B〜2＃SIGMA＃〜+，v = 0，N）+ H_2，CN（X〜2＃SIGMA＃〜+，v = 2，N）的状态对状态和总旋转能量传输速率常数+ H_2，D_2和CN（X〜2＃SIGMA＃〜+，v = 3，N）+ NO
3. RATE COEFFICIENT FOR H~+ + H_2(X~1∑_g~+, v = 0, J = 0) → H(1s)) + H_2~+ CHARGE TRANSFER AND SOME COSMOLOGICAL IMPLICATIONS [J] . DANIEL WOLF SAVIN, PREDRAG S. KRSTIC, ZOLTAN HAIMAN, The Astrophysical journal . 2004,第2aaParta2期

机译：H〜+ + H_2（X〜1∑_g〜+，v = 0，J = 0）→H（1s））+ H_2〜+电荷转移及某些宇宙学意义的速率系数
4. Influence of Proton Activity Gaps between Electrodes on Open-Circuit Potential of H_2/H_2 and H_2/Air Cells [C] . Toshihiko Yoshida, TaKemasa Hojo, Tetsuya Jozuka, Pacific Rim Meeting on Electrochemical and Solid-State Science . 2020

机译：质子活性间隙电极之间的影响H_2 / h_2和H_2 /空气电池的开路电位
5. TIME DEPENDENT FLUORESCENCE DEPOLARIZATION AND BROWNIAN ROTATIONAL DIFFUSION COEFFICIENTS OF MACROMOLECULES. [D] . TAO, TERENCE CHI CHEUNG. 1969

机译：大分子的时间依赖性荧光去极化和布朗旋转扩散系数。
6. Rotationally inelastic dynamics of LiH (X1Σ+ v = 0) in collisions with Ar: State-to-state inelastic rotational rate coefficients [O] . Aliou Niane, Cheikh Amadou Bamba Dath, Ndèye Arame Boye Faye, -1

机译：与Ar碰撞时LiH（X1Σ+v in = 0）的旋转非弹性动力学：状态间非弹性旋转速率系数
7. Rotational quenching rate coefficients for H_2 in collisions with H_2 from 2 to 10,000 K [O] . Lee, T. -G., Balakrishnan, N., Forrey, R. C., 2008

机译：H_2与H_2碰撞时的旋转淬火速率系数从2到10,000 K.

Rotational Quenching Rate Coefficients For H_2 In Collisionswith H_2 From 2 To 10,000 K

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