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首页> 外文期刊>Atmospheric environment >Calibration of polydimethylsiloxane and XAD-Pocket passive air samplers (PAS) for measuring gas- and particle-phase SVOCs
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Calibration of polydimethylsiloxane and XAD-Pocket passive air samplers (PAS) for measuring gas- and particle-phase SVOCs

机译：校准用于测量气相和颗粒相SVOC的聚二甲基硅氧烷和XAD口袋式无源空气采样器（PAS）

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摘要

Polydimethylsiloxane (PDMS) has seen wide use as the stationary phase of gas chromatographic columns, a passive sampler in water, and recently as a personal exposure sampler, while styrene divinylbenzene copolymer (XAD) has been used extensively as a passive air sampler outdoors and indoors. We have introduced PDMS and XAD-Pocket as new indoor passive air samplers (PASs). The XAD-Pocket was designed to maximize the surface area-to-volume ratio of XAD and to minimize obstruction of air flow by the sampler housing. Methods were developed to expedite the use of these PASs for measuring phthalates, novel brominated flame-retardants (NFRs) and polybrominated diphenyl ethers (PBDEs) indoors. Sampling rates, Rs, (m(3) day(-1)), were measured during a 7-week calibration study. Variability within and between analyte groups was not statistically significant. As a result, generic values of 0.8 +/- 0.4 and 0.5 +/- 03 m(3) day(-1) dm(-2) are recommended for PDMS and XAD-Pocket for a 50-day deployment time, respectively. PDMS has a higher uptake rate and is easier to use than XAD-Pocket. (C) 2016 Elsevier Ltd. All rights reserved.
机译：聚二甲基硅氧烷（PDMS）已广泛用作气相色谱柱的固定相，水中的被动采样器，最近又用作个人暴露采样器，而苯乙烯二乙烯基苯共聚物（XAD）已在室外和室内广泛用作被动空气采样器。我们已经引入了PDMS和XAD-Pocket作为新的室内被动空气采样器（PAS）。 XAD-Pocket旨在最大程度地提高XAD的表面积/体积比，并最大程度减少采样器外壳对气流的阻碍。已开发出方法来加快这些PAS在室内测量邻苯二甲酸盐，新型溴化阻燃剂（NFR）和多溴联苯醚（PBDEs）的速度。在为期7周的校准研究中测量了采样率Rs（m（3）天（-1））。分析物组内和之间的差异在统计学上不显着。因此，对于PDMS和XAD-Pocket，建议分别在50天的部署时间内使用0.8 +/- 0.4和0.5 +/- 03 m（3）day（-1）dm（-2）的通用值。与XAD-Pocket相比，PDMS的吸收率更高并且更易于使用。 （C）2016 Elsevier Ltd.保留所有权利。

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  • 来源
    《Atmospheric environment》 |2016年第10期|202-208|共7页
  • 作者

    Okeme Joseph O.; Saini Amandeep; Yang Congqiao; Zhu Jiping; Smedes Foppe; Klanova Jana; Diamond Miriam L.;

  • 作者单位

    Univ Toronto Scarborough, Dept Phys & Environm Sci, 1265 Mil Trail, Toronto, ON M1C 1A4, Canada;

    Univ Toronto Scarborough, Dept Phys & Environm Sci, 1265 Mil Trail, Toronto, ON M1C 1A4, Canada;

    Univ Toronto, Dept Earth Sci, 22 Russell St, Toronto, ON M5S 3B1, Canada;

    Hlth Canada, Exposure & Biomonitoring Div, Ottawa, ON K1A 0K9, Canada;

    Masaryk Univ, Fac Sci, Res Ctr Tox Cpds Environm RECETOX, Kamenice 753-5, CZ-62500 Brno, Czech Republic;

    Masaryk Univ, Fac Sci, Res Ctr Tox Cpds Environm RECETOX, Kamenice 753-5, CZ-62500 Brno, Czech Republic;

    Univ Toronto Scarborough, Dept Phys & Environm Sci, 1265 Mil Trail, Toronto, ON M1C 1A4, Canada|Univ Toronto, Dept Earth Sci, 22 Russell St, Toronto, ON M5S 3B1, Canada;

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  • 原文格式 PDF
  • 正文语种 eng
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  • 关键词

    Passive sampling; Calibration; PDMS; XAD-Pocket; Phthalates; Flame-retardants;

    机译：被动采样;校准;PDMS;XAD袋;邻苯二甲酸盐;阻燃剂;

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