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The Treasure Valley secondary aerosol study I: measurements and equilibrium modeling of inorganic secondary aerosols and precursors for southwestern Idaho

机译:金银谷二次气溶胶研究I:西南爱达荷州无机二次气溶胶和前驱物的测量和平衡模型

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The SCAPE2 aerosol equilibrium model was applied to measured concentrations Of PM2.5 aerosol and precursor gases. Ambient measurements in the Treasure Valley, Idaho were collected during stagnation episodes between December 1999 and March 2000 when conditions were favorable for the formation of secondary inorganic aerosol. SCAPE2 results agreed well with measurements for the episodes tested; Monte Carlo simulation using the uncertainties of the model input variables indicated that discrepancies between measured and modeled results were within the range of analytical precision. Air pollution control strategies were evaluated by perturbing the model input concentrations of total sulfate, nitrate, and ammonium. The largest reductions in secondary aerosol concentrations occurred when total nitrate was reduced, indicating that the formation of ammonium nitrate was limited by the availability of nitrate. (C) 2002 Elsevier Science Ltd. All rights reserved. [References: 39]
机译:将SCAPE2气溶胶平衡模型应用于测得的PM2.5气溶胶和前体气体的浓度。爱达荷州金银谷的环境测量值是在1999年12月至2000年3月停滞期间收集的,当时条件有利于形成二次无机气溶胶。 SCAPE2结果与测试发作的测量结果非常吻合;使用模型输入变量的不确定性进行的蒙特卡洛模拟表明,测量结果和建模结果之间的差异在分析精度范围内。通过扰动总硫酸盐,硝酸盐和铵的模型输入浓度来评估空气污染控制策略。当总硝酸盐减少时,次级气溶胶浓度的减少最大,表明硝酸铵的形成受到硝酸盐可用性的限制。 (C)2002 Elsevier Science Ltd.保留所有权利。 [参考:39]

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