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Antifouling performance of copper-containing fused filament fabrication (FFF) 3-D printing polymer filaments for marine applications

机译:用于含铜熔丝制造(FFF)3-D印刷聚合物长丝的防污性能用于海洋应用

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摘要

3-D printing allows for rapid prototyping and manufacture of components in a cost effective and timely manner, becoming a popular technology for oceanographic and maritime engineering applications. However, 3-D printed components are at risk of accumulating marine biofouling. This study examined the antifouling (AF) performance of three Cu-containing 3-D printing polymer filaments for potential marine use. The amount of Cu present in each filament was the primary determinant of AF performance. The lowest Cu-content (30%) filament recording 29% biofouling cover after 1 month and near 100% cover after 3 months. These AF results were comparable to polylactide acid (PLA) and acrylonitrile butadiene styrene (ABS) polymer filament controls. The medium (50%) Cu-content filament remained largely free of biofouling until 3 months (where 48% coverage was observed), after which fouling cover increased to 100% by similar to 12 months. The highest Cu-content (80%) filament remained free of all macrofouling for the entire 24 months of the experiment.
机译:3-D印刷允许以成本效益和及时的方式快速原型和制造组件,成为海洋和海洋工程应用的流行技术。然而,3-D印刷组件面临着积累海洋生物污染的风险。该研究检测了用于潜在海洋使用的三种Cu的3-D印刷聚合物长丝的防污(AF)性能。每个长丝中存在的Cu的量是AF性能的主要决定因素。最低的Cu含量(30%)长丝在1个月后记录29%的生物污垢盖,3个月后覆盖近100%。这些AF结果与聚丙酰基酸(PLA)和丙烯腈丁二烯苯乙烯(ABS)聚合物长丝对照相当。培养基(50%)Cu - 含量长丝仍然大部分不含生物污垢直至3个月(观察到48%的覆盖率),之后,在相似的污染覆盖率增加至100%以上。最高的Cu-含量(80%)丝仍然没有所有24个月的Macrofouling实验。

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