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Effect of Ca/P electrolyte concentration on MAO biofilm on Ti alloy surface

机译:Ca / P电解质浓度对Ti合金表面MAO生物膜的影响

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摘要

In order to prepare functional films containing a predetermined ratio of calcium (Ca) and phosphorus (P) and guide the rational allocation of chemical reagents on a titanium (Ti) alloy surface, calcium/phosphorus biological films were fabricated by using the microarc oxidation (MAO) process. The films' morphology and elemental composition were observed and analyzed. Moreover, a wear resistance test was performed on the film surface. The influence of different concentrations and calcium/phosphorus molar ratios of the films and the MAO system were researched. The effects of electrolyte concentration on the calcium/phosphorus molar ratio of the films were also investigated. The experimental results show that with an increase in electrolyte concentration, the calcium and phosphorus contents of the films all decreased, but the calcium/phosphorus ratio increased. Similarly, the values of the calcium/phosphorus molar ratio and the calcium and phosphorus contents in the films all became lower. Furthermore, a proper electrolyte concentration is helpful in improving the surface properties of the films. If preparation of a film with a certain calcium/phosphorus molar ratio is wanted, this certain ratio can determine the different electrolyte molar concentrations of calcium/phosphorus and it can roughly determine the ratio of the compound reagent and improve the test efficiency.
机译:为了制备包含预定比例的钙(Ca)和磷(P)的功能膜并指导化学试剂在钛(Ti)合金表面上的合理分配,通过使用微弧氧化法制备了钙/磷生物膜( MAO)过程。观察并分析了膜的形态和元素组成。此外,在膜表面上进行了耐磨性测试。研究了不同浓度和钙/磷摩尔比对薄膜和MAO体系的影响。还研究了电解质浓度对薄膜钙/磷摩尔比的影响。实验结果表明,随着电解质浓度的增加,膜中钙,磷含量均降低,但钙磷比增加。类似地,膜中钙/磷摩尔比的值以及钙和磷含量均变低。此外,适当的电解质浓度有助于改善膜的表面性质。如果需要制备具有一定钙/磷摩尔比的薄膜,则该一定比率可以确定不同电解质电解质中钙/磷的摩尔浓度,并且可以粗略确定化合物试剂的比率并提高测试效率。

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