首页> 外文期刊>High temperature materials and processes >A Comparative Study of the Corrosion Behavior of Three Stainless Steels in an Eutectic (Li,Na,K>2CO_3 Melt with and without (Na,K)Cl Additives at 973 K in Air
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A Comparative Study of the Corrosion Behavior of Three Stainless Steels in an Eutectic (Li,Na,K>2CO_3 Melt with and without (Na,K)Cl Additives at 973 K in Air

机译:三种不锈钢在含和不含(Na,K)Cl添加剂的共晶(Li,Na,K> 2CO_3熔体)中在空气中的腐蚀行为的比较研究

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摘要

The ternary carbonate eutectic mixture of Li_2CO_3, K_2CO_3 and Na_2CO_3 as a heat transfer and storage medium has excellent thermophysical properties, but with high viscidity as compared with some other inorganic salts such as chlorides and nitrates. The addition of chlorides or fluorides to molten carbonates may improve their fluidity, but possibly making the melt become more corrosive. In this study, the corrosion behavior of type 304, 310 and 316 stainless steels in an eutectic (Li,Na,K)_2CO_3 melt with and without an eutectic mixture of 'NaCl and KC1 at 973K in air have been examined. The experimental results indicated that 310 steel shows a much better corrosion resistance in molten carbonates than both 304 and 316 steels, due to the formation of a continuous LiCrO_2 scale. The addition of chlorides to carbonates melt accelerated the corrosion of the steels, especially 310 steel, producing scales with more porosity.
机译:作为传热和存储介质的Li_2CO_3,K_2CO_3和Na_2CO_3的三元碳酸盐共晶混合物具有出色的热物理性质,但与某些其他无机盐(如氯化物和硝酸盐)相比具有较高的粘度。向熔融碳酸盐中添加氯化物或氟化物可以改善其流动性,但可能会使熔体变得更具腐蚀性。在这项研究中,研究了304、310和316型不锈钢在有和没有'NaCl和KCl的共晶混合物在973K空气中的共熔(Li,Na,K)_2CO_3熔体中的腐蚀行为。实验结果表明,由于形成连续的LiCrO_2氧化皮,310钢在熔融碳酸盐中的耐蚀性比304和316钢都好。向碳酸盐中添加氯化物会加速钢尤其是310钢的腐蚀,从而产生具有更高孔隙率的氧化皮。

著录项

  • 来源
    《High temperature materials and processes》 |2011年第2期|p.161-169|共9页
  • 作者

    C. L. Zeng; Y.Liu;

  • 作者单位

    State Key Laboratory for Corrosion and Protection, Insti-tute of Metal Research, Chinese Academy of Sciences,Shenyang, China;

    State Key Laboratory for Corrosion and Protection, Insti-tute of Metal Research, Chinese Academy of Sciences,Shenyang, China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    stainless steels; (li; na; k)_2co_3; (na; k)cl; molten salts corrosion;

    机译:不锈钢;(li;na;k)_2co_3;(na;k)cl;熔融盐腐蚀;

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