Vapor Pressure Measurements of Phosphorus in Cu-P Alloys by Knudsen Cell Mass Spectrometry

Woong-Hee Han; Masao Miyake; Yoshitaka Mitsuda

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Vapor Pressure Measurements of Phosphorus in Cu-P Alloys by Knudsen Cell Mass Spectrometry

机译：Knudsen细胞质谱法测量Cu-P合金中磷的蒸气压

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The vapor pressures of phosphorus (P) in Cu-P alloys with concentrations less than 4.4 mol percent P at temperatures between 1202 and 1476 K were investigated by double Knudsen cell mass spectrometry using Cu-0.47 mol percent P alloy as a reference substance. The P_2 pressures of the liquid and solid alloy could be measured. The series of P_2 pressures obtained in this study was consistent with that thermodynamically expected from the phase diagram.

机译：通过双克努森细胞质谱法，以Cu-0.47 mol％P合金为参考物质，研究了浓度小于4.4 mol％P的Cu-P合金中磷（P）在1202和1476 K之间的温度下的蒸气压。可以测量液态和固态合金的P_2压力。在这项研究中获得的一系列P_2压力与相图中的热力学预期一致。

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来源
《High temperature materials and processes》 |2004年第6期|p.399-403|共5页
作者
Woong-Hee Han; Masao Miyake; Yoshitaka Mitsuda;
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作者单位

Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-Ku, Tokyo 153-8505, Japan;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类金属学与热处理;
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8. Double Knudsen cell system for alloy activity measurements by mass spectrometry [R] . Jacobson, Nathan S. 1995

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Vapor Pressure Measurements of Phosphorus in Cu-P Alloys by Knudsen Cell Mass Spectrometry

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