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Predictive modeling and design rules for solid electrolytes

机译:固体电解质的预测建模和设计规则

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摘要

All-solid-state batteries utilizing a ceramic instead of an organic liquid as an electrolyte have the potential to be safer and more energy dense than traditional rechargeable lithium-ion batteries. This emergent energy-storage technology, however, is still critically limited by the performance of the solid electrolyte and its interface with electrodes. Here, we present a review of recent efforts in predictive modeling and materials design for lithium and sodium solid electrolytes using advanced computational approaches. These approaches have enabled the efficient design and discovery of new functional materials with desired properties, such as high alkali ionic conductivity, good phase and electrochemical stability, and low cost, accelerating the development of all-solid-state alkali batteries.
机译:与传统的可再充电锂离子电池相比,采用陶瓷代替有机液体作为电解质的全固态电池具有更安全,能量密度更高的潜力。然而,这种新兴的能量存储技术仍然受到固体电解质的性能及其与电极的界面的严格限制。在这里,我们介绍了使用先进的计算方法在锂和钠固体电解质的预测建模和材料设计方面所做的最新工作。这些方法使得能够有效设计和发现具有所需特性的新功能材料,例如高碱离子导电性,良好的相和电化学稳定性以及低成本,从而加速了全固态碱电池的开发。

著录项

  • 来源
    《MRS bulletin》 |2018年第10期|746-751|共6页
  • 作者单位

    Univ Calif Berkeley, Mat Sci &

    Engn, Berkeley, CA 94720 USA.;

    Univ Calif San Diego, Nanoengn, San Diego, CA 92103 USA.;

    Samsung Res Amer, Adv Mat Lab, Mountain View, CA USA.;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    energy storage; ionic conductor; simulation;

    机译:储能;离子导体模拟;

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