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Organic matter source discrimination by humic acid characterization: Synchronous scan fluorescence spectroscopy and Ferrate(VI)

机译:腐植酸表征有机物来源的鉴别:同步扫描荧光光谱法和高铁酸盐(VI)

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摘要

In this study, seven soil and sedimentary humic acid samples were analyzed by synchronous scan fluorescence (SSF) spectroscopy. The spectra of these humic acids were compared to each other and characterized, based on three major SSF peaks centered at approximately 281,367 and 470 nm. Intensity ratios were calculated based on these peaks that were used to numerically assist in source discrimination. All humic acid samples were then reacted with Ferrate(VI) and were again analyzed with SSF. Upon the addition of Ferrate(VI) SSF spectra were obtained which more readily differentiated humic acid source. This method will assist geochemists and water management districts in tracing sources of organic matter to receiving water bodies and may aid in the elucidation of the chemical nature of humic acids.
机译:在这项研究中,通过同步扫描荧光(SSF)光谱分析了七个土壤和沉积性腐殖酸样品。基于位于约281,367和470 nm处的三个主要SSF峰,对这些腐殖酸的光谱进行了相互比较和表征。基于这些峰值计算强度比,这些峰值用于在数值上帮助识别源。然后将所有腐殖酸样品与高铁酸盐(VI)反应,并再次用SSF分析。加入高铁酸盐(VI)后,SSF光谱得到了更容易区分的腐殖酸来源。这种方法将帮助地球化学家和水管理区寻找有机物质的来源,以寻找接收水体,并可能有助于阐明腐殖酸的化学性质。

著录项

  • 来源
    《Chemosphere》 |2013年第6期|2013-2019|共7页
  • 作者单位

    Department of Environmental Science, Florida Institute of Technology, 150 West University Boulevard, Melbourne, FL 32901, USA;

    Department of Chemistry, Florida Institute of Technology, 150 West University Boulevard, Melbourne, FL 32901, USA;

    Department of Chemistry, Florida Institute of Technology, 150 West University Boulevard, Melbourne, FL 32901, USA;

    Department of Chemistry, Florida Institute of Technology, 150 West University Boulevard, Melbourne, FL 32901, USA;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    humic acid; synchronous scan fluorescence; ferrate(VI); organic matter source discrimination;

    机译:腐植酸;同步扫描荧光高铁酸盐(VI);有机物来源歧视;

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