Combustion energies and standard molar enthalpies of formation for the complexes of the first-row transitional metal chlorides with L-α-histidine

GAO Shengli; CHEN Sanping; YANG Xuwu; SHI Qizhen

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Combustion energies and standard molar enthalpies of formation for the complexes of the first-row transitional metal chlorides with L-α-histidine

机译：第一行过渡金属氯化物与L-α-组氨酸的配合物的燃烧能和标准摩尔生成焓

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Seven novel solid complexes of the first-row transitional metal with L-α -histidine were synthesized, and their compositions were determined. The constant-volume combustion energies of the complexes were measured by a precision rotation bomb calorimeter. The standard molar enthalpies of combustion and the standard molar enthalpies of formation were calculated. The results indicated that the plots of the standard enthalpies of formation against the atomic number of the metal show a regularity of zigzag.

机译：合成了第一行过渡金属与L-α-组氨酸的7种新型固体配合物，并确定了其组成。通过精密旋转炸弹量热仪测量络合物的恒定体积燃烧能量。计算燃烧的标准摩尔焓和地层的标准摩尔焓。结果表明，标准形成焓与金属原子序数的关系曲线呈锯齿状。

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来源
《Chinese science bulletin》 |2003年第4期|p.319-322|共4页
作者
GAO Shengli; CHEN Sanping; YANG Xuwu; SHI Qizhen;
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作者单位

Shaanxi Key Laboratory of Physic-Inorganic Chemistry/Chemistry Department of Northwest University, Xi'an 710069, China;

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正文语种 eng
中图分类自然科学现状及发展;
关键词
transitional metal chloride; L-α -histidine; solid complex; standard molar enthalpies of formation;

机译：过渡金属氯化物L-α-组氨酸固体配合物标准摩尔形成焓;

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Combustion energies and standard molar enthalpies of formation for the complexes of the first-row transitional metal chlorides with L-α-histidine

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