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Inner-tubular physicochemical processes of carbon nanotubes

机译：碳纳米管的管内理化过程

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摘要

Nanosized inner cavities of carbon nanotubes (CNTs) afford quasi-one-dimensional (1D) confined space, in which materials adsorbed or filled are of reactivity greatly different from the materials adsorbed on a planar surface and quite a number of curious physicochemical processes will possibly occur. In other words, 1D CNT nanochannels may serve as "nanosized test tubes". In this article, on the basis of the unique chemical and physical properties of CNTs, the latest progresses of the research on peculiar inner-tubular physicochemical processes of CNTs are briefly reviewed from several aspects. The extraordinary ID adsorption, capillary filling and nanoscale-confined reaction are discussed in detail. Moreover, the characteristics of "nanosized test tubes" are summarized and many unfamiliar inner cavity chemical processes are expected. Finally, the future direction and challenges on basic researches and potential applications of inner-tubular chemistry of CNTs are discussed.
机译：碳纳米管（CNT）的纳米级内腔提供了准一维（1D）密闭空间，其中吸附或填充的材料的反应性与吸附在平面表面上的材料有很大不同，并且可能会有许多奇怪的理化过程发生。换句话说，一维CNT纳米通道可以用作“纳米试管”。本文基于碳纳米管独特的化学和物理性质，从几个方面简要回顾了碳纳米管特殊的管内理化过程的研究进展。详细讨论了非常规ID吸附，毛细管填充和纳米级受限反应。此外，总结了“纳米试管”的特性，并期望许多不熟悉的内腔化学过程。最后，讨论了碳纳米管内管化学的基础研究和潜在应用的未来方向和挑战。

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