The adsorption of 2, 5-dimer- capto-1, 3, 4-thiadiazole (DMTD) on copper surface and its binding behavior

HUANG Ling; SHEN Jian; REN Jun

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The adsorption of 2, 5-dimer- capto-1, 3, 4-thiadiazole (DMTD) on copper surface and its binding behavior

机译：2,5-二聚-巯基-1,3,4-噻二唑（DMTD）在铜表面的吸附及其结合行为

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The interaction mechanism of 2, 5-dimercapto- 1, 3, 4-thiadiazole (DMTD) on copper surface was studied by surface-enhanced Raman scattering (SERS), infrared (IR) and X-ray photoelectron spectroscopy (XPS) techniques. The SERS spectra were obtained. We found that DMTD bound With the copper via its two-excocyclic mercapto groups. The Monosulphide salt was formed. At the same time, DMTD Coordinated with the Cu ion through the excocyclic mer- Capto groups and polymerized via the Cu ion into a one - Dimensional polymer chain on the copper surface.

机译：通过表面增强拉曼散射（SERS），红外（IR）和X射线光电子能谱（XPS）技术研究了2,5-二巯基-1,3,4-噻二唑（DMTD）在铜表面的相互作用机理。获得了SERS光谱。我们发现DMTD通过其两个外环巯基与铜结合。形成了单硫化物盐。同时，DMTD通过环外巯基与铜离子配位，并通过铜离子聚合成铜表面的一维聚合物链。

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《Chinese science bulletin》 |2001年第5期|p.387-389|共3页
作者
HUANG Ling; SHEN Jian; REN Jun;
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正文语种 eng
中图分类自然科学现状及发展;
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2, 5-dimercapto-1, 3, 4-thiadiazole (DMTD); surface-en- hanced Raman scattering (SERS); adsorption and binding.;

机译：2;5;5-二巯基-1;3;4-噻二唑（DMTD）;表面增强拉曼散射（SERS）;吸附和结合。;

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1. Surface selective binding of 2,5-dimercapto-1,3,4-thiadiazole (DMTD) on silver and gold nanoparticles: a Raman and DFT study [J] . Maiti Nandita, Chadha Ridhima, Das Abhishek, RSC Advances . 2016,第67期

机译：2,5-Dimercapto-1,3,4-噻二唑（DMTD）的表面选择性结合银和金纳米粒子：拉曼和DFT研究
2. Surface selective binding of 2,5-dimercapto-1,3,4-thiadiazole (DMTD) on silver and gold nanoparticles: a Raman and DFT study [J] . Nandita Maiti, Ridhima Chadha, Abhishek Das, RSC Advances . 2016,第67期

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The adsorption of 2, 5-dimer- capto-1, 3, 4-thiadiazole (DMTD) on copper surface and its binding behavior

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