Crystal and molecular structures of ε-HNIW

ZHAO Xinqi; SHI Nicheng

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Crystal and molecular structures of ε-HNIW

机译：ε-HNIW的晶体和分子结构

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There is a growing interest in HNIW (Hexanitrohexaazaisowurtzitane, CL-20) prepared by Nielsen in 1987. It is said that its explosive properties are superior to those of Octogen (HMX), the best high explosive at present. Its application will improve performance characteristics of conventional weapons. HNIW at ambient pressure and temperature exists in four polymorphic modifications: α, β, γ and ε. Among them ε-HNIW possesses the highest crystal density. We report for the first time the crystal and molecular structures of the title compound.

机译：1987年尼尔森（Nielsen）制备的HNIW（六硝基六氮杂异纤锌矿型结构烷烃，CL-20）受到越来越多的关注。据说，它的爆炸性能优于目前最好的高炸药Octogen（HMX）。它的应用将改善常规武器的性能特征。 HNIW在环境压力和温度下存在四个多态变体：α，β，γ和ε。其中，ε-HNIW具有最高的晶体密度。我们首次报告了标题化合物的晶体和分子结构。

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来源
《Chinese science bulletin》 |1996年第7期|p.574-576|共3页
作者
ZHAO Xinqi; SHI Nicheng;
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作者单位

Department of Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China;

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原文格式 PDF
正文语种 eng
中图分类自然科学现状及发展;
关键词
HNIW; crystal structure; high energy density material;

机译：HNIW;晶体结构;高能量密度材料;

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专利

1. Crystal and molecular structures of ε-HNIW [J] . ZHAO Xinqi, SHI Nicheng Chinese science bulletin . 1996,第7期

机译：ε-HNIW的晶体和分子结构
2. Structure, equation of state and elasticity of crystalline HNIW by molecular dynamics simulations [J] . Tan J.-J., Ji G.-F., Chen X.-R., Physica, B. Condensed Matter . 2011,第15a16期

机译：分子动力学模拟结晶HNIW的结构，状态方程和弹性
3. Energetic materials: variable-temperature crystal structures of gamma- and epsilon-HNIW polymorphs [J] . Bolotina NB, Hardie MJ, Speer RL, Journal of Applied Crystallography . 2004,第5期

机译：含能材料：γ-和ε-HNIW多晶型物的可变温度晶体结构
4. CRYSTAL ENGINEERING OF HNIW BY MOLECULAR MODELING USING GENMOL [C] . S. Benazet, G. Jacob, G. Pepe International annual conference of ICT . 2002

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8. Molecular Packing and NPT-Molecular Dynamics Investigation of the Transferabilityof the RDX Intermolecular Potential to 2,4,6,8,10,12-Hexanitr ohexaazaisowurtzitane (HNIW) [R] . SOrescu, D. C., Thompson, D. L., Rice, B. M. 1998

机译：分子包装和NpT-分子动力学研究RDX分子间势向2,4,6,8,10,12-己烷ohexaazaisowurtititane（HNIW）的转移性

Crystal and molecular structures of ε-HNIW

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