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A study of tungsten nanopowder formation by self-propagating high-temperature synthesis

机译:自蔓延高温合成钨纳米粉体的研究

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Molten salt-assisted self-propagating high-temperature synthesis of nanocrystalline W powder was studied experimentally. The technique involves the reduction of WO_3 in the presence of sodium chloride using three different reducing agents: magnesium (Mg), sodium azide (NaN_3), and sodium borohydride (NaBH_4). The effects of the mole fraction of sodium chloride on temperature distributions, combustion parameters, phase compositions, and morphology of the final products were determined. The sodium chloride-assisted method reported here has been found to be effective for lowering combustion temperature and producing uniform and spherical W nanopow-ders of average particle size around 20-200, 100-200, and 20-50 nm. The effect of combustion temperature on tungsten particle size is discussed, and a sketch describing the chemistry of combustion is proposed.
机译:实验研究了熔融盐辅助自蔓延高温合成纳米晶W粉的过程。该技术涉及使用三种不同的还原剂在氯化钠存在下还原WO_3:镁(Mg),叠氮化钠(NaN_3)和硼氢化钠(NaBH_4)。确定了氯化钠的摩尔分数对温度分布,燃烧参数,相组成和最终产物形态的影响。已发现此处报道的氯化钠辅助方法可有效降低燃烧温度并生产平均粒径约为20-200、100-200和20-50 nm的均匀球形W纳米粉。讨论了燃烧温度对钨粒度的影响,并提出了描述燃烧化学的草图。

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