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Thermal, mechanical, morphological, thermogravimetric, rheological and toxicological behavior of HDPE/seaweed residues composites

机译:HDPE /海藻渣复合材料的热,机械,形态,热重,流变和毒理行为

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摘要

The objective of this research was to study the thermal, mechanical, rheological and toxicological behavior of high-density polyethylene composites filled with seaweed residues (SR) at different compositions (10, 20, 30, 40 wt%), using Lica 12 as coupling agent at concentrations between 0 and 1.0 wt%. From the thermal analysis, it can be inferred that crystallinity increased with filler content as well as crystallization temperatures. The initial decomposition temperature of materials did not show significant changes varying between 482 and 485℃. Regarding the mechanical behavior, a slight increase in Young's modulus from 652 to 738 MPa was observed. Elongation at break decreased drastically from 1000% to 20% while strength at break remained approximately constant. Melt flow index decreased from 5.08 to 3.57 g/10 min. Based on the results, it is possible to select any filler content as a candidate for bone substitute material. Therefore, for toxicity studies we chose 40% composite. The inclusion of SR in polymeric matrix proved to be biocompatible with animal tissue, showing no adverse reactions, which allows its possible application in biomedicine.
机译:这项研究的目的是使用Lica 12作为偶联剂,研究不同密度(10、20、30、40 wt%)填充有海藻残渣(SR)的高密度聚乙烯复合材料的热,机械,流变和毒理行为。剂的浓度在0至1.0重量%之间。从热分析中可以推断出,结晶度随填料含量以及结晶温度的增加而增加。材料的初始分解温度在482和485℃之间没有显着变化。关于机械性能,观察到杨氏模量从652MPa轻微增加到738MPa。断裂伸长率从1000%急剧下降至20%,而断裂强度保持大致恒定。熔体流动指数从5.08降至3.57 g / 10 min。根据结果​​,可以选择任何填料含量作为骨替代材料的候选材料。因此,对于毒性研究,我们选择40%复合材料。在聚合物基质中包含SR被证明与动物组织具有生物相容性,没有任何不良反应,这使其可能在生物医学中得到应用。

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