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首页> 外文期刊>Contributions to Mineralogy and Petrology >Kokchetavite: a new potassium-feldspar polymorph from the Kokchetav ultrahigh-pressure terrane
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Kokchetavite: a new potassium-feldspar polymorph from the Kokchetav ultrahigh-pressure terrane

机译:Kokchetavite:来自Kokchetav超高压地层的新型钾长石多晶型物

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摘要

Kokchetavite, a new polymorph of K-feldspar (KAlSi3O8), has been identified as micrometer-size inclusions in clinopyroxene and garnet in a garnet-pyroxene rock from the Kokchetav ultrahigh-pressure terrane, Kazakhstan. Kokchetavite has a hexagonal structure with a =5.27(1) Å, c=7.82(1) Å, V=188.09 Å3, Z=1, and is found to be associated with phengite + α/β-cristobalite (or quartz) + siliceous glass ± phlogopite/titanite/calcite/zircon, occurring as multi-phase inclusions in clinopyroxene and garnet. It is concluded that kokchetavite could not be an exsolution phase in host minerals. Instead, it might be metastably precipitated from an infiltrated K-rich melt during rock exhumation. Alternatively, although less likely, kokchetavite might be derived from dehydration of K-cymrite, which, in turn, was formed at high pressures. In either case, kokchetavite is a metastable polymorph of K-feldspar.
机译:Kokchetavite是钾长石(KAlSi3 O8 )的一种新的多晶型物,已被确定为哈萨克斯坦Kokchetav超高压地层的石榴石-辉石岩中斜长石和石榴石中微米级的包裹体。 Kokchetavite具有六边形结构,其结构为= 5.27(1)Å,c = 7.82(1)Å,V = 188.09Å3,Z = 1,并且被发现与辉石+α/β-方英石(或石英)+硅质玻璃±金云母/钛铁矿/方解石/锆石,以多相夹杂物形式存在于斜辉石和石榴石中。结论是,kokchetavite不可能是宿主矿物中的析出相。取而代之的是,它可能在岩石挖掘过程中从渗透的富K熔体中转移出来。另外,尽管可能性不大,但kokchetavite可能是由K-硫铁矿的脱水产生的,而K-硫铁矿的脱水又是在高压下形成的。无论哪种情况,kokchetavite都是钾长石的亚稳态多晶型物。

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