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Metallacyclic assembly of interlocked superstructures

机译:互锁上层建筑的金属环组装

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摘要

Interlocked molecules are a type of supramolecules whose sub-components are held together not by covalent bonds but non-covalent interactions. Examples include rotaxanes, catenanes, Solomon links, ring-in-ring complexes, molecular Borromean rings, molecular knots and interlocked cages. The design and manufacture of these architectures is mainly based on self-assembly and template-directed methodologies. Inspired by the successful utilization of coordination-driven assembly in metallasupramolecular systems, the metallacyclic assembly of interlocked superstructures is developing rapidly and as such makes a fascinating topic for reviewing. In this review we will focus on the metal-directed synthesis of the different types of interlocked superstructures, as well as their functional applications. (C) 2016 Elsevier B.V. All rights reserved.
机译:互锁分子是一种超分子,其子成分不是通过共价键而是通过非共价相互作用保持在一起。实例包括轮烷,链烷,所罗门链,环中环的络合物,分子硼烷环,分子结和互锁的笼子。这些体系结构的设计和制造主要基于自组装和模板指导的方法。受金属超分子系统中协调驱动组装的成功利用的启发,互锁上层建筑的金属环组装正在迅速发展,因此成为令人着迷的主题。在这篇综述中,我们将重点研究金属互锁的上层建筑的金属化合成及其功能应用。 (C)2016 Elsevier B.V.保留所有权利。

著录项

  • 来源
    《Coordination chemistry reviews》 |2017年第2期|1-26|共26页
  • 作者单位

    Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Dept Chem, Collaborat Innovat Ctr Chem Energy Mat, Shanghai 200433, Peoples R China;

    Univ Hong Kong, Dept Chem, Pokfulam Rd, Hong Kong, Hong Kong, Peoples R China;

    Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Dept Chem, Collaborat Innovat Ctr Chem Energy Mat, Shanghai 200433, Peoples R China;

  • 收录信息 美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Interlocked; Metallasupramolecules; Coordination-driven assembly; Supramolecular chemistry;

    机译:互锁;金属超分子;配位驱动的组装;超分子化学;

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