Inverse coordination - An emerging new chemical concept. Oxygen and other chalcogens as coordination centers

Haiduc Ionel

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Inverse coordination - An emerging new chemical concept. Oxygen and other chalcogens as coordination centers

机译：反配位-一个新兴的化学新概念。氧气和其他硫属元素作为协调中心

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Inverse coordination is the formation of metal complexes in which the arrangement of acceptor and donor sites is opposite to that occurring in conventional coordination complexes. Inverse coordination complexes are formed around a non-metal species as central atom (ion) surrounded by a number of metal atoms (ions) connected or not by internal bridging (intramolecular) linkers. This review presents a panorama of inverse coordination structures and illustrates the diversity of species which can be described under this concept. Structures are presented in which coordination centers are oxygen and the other chalcogens (sulfur, selenium, tellurium). (C) 2017 Elsevier B.V. All rights reserved.

机译：逆配位是金属络合物的形成，其中受体和施主位点的排列与常规配位络合物中的排列相反。逆配位络合物在非金属物质周围形成为中心原子（离子），该中心原子（离子）被内部桥接（分子内）连接子连接或不连接的多个金属原子（离子）包围。这项审查提出了逆向协调结构的全景图，并说明了可以在此概念下描述的物种多样性。提出的结构中，配位中心是氧和其他硫属元素（硫，硒，碲）。（C）2017 Elsevier B.V.保留所有权利。

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来源
《Coordination chemistry reviews》 |2017年第5期|1-26|共26页
作者
Haiduc Ionel;
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作者单位

Univ Babes Bolyai, Fac Chim, Str. Arany Janos 11, Cluj Napoca 400028, Romania;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
Inverse coordination; Metal complexes; Molecular topology; Chalcogens; Oxo-centered; Trinuclear; Tetranuclear; Complex; Sulfur; Selenium; Tellurium;

机译：逆配位;金属配合物;分子拓扑;硫属元素化合物;以氧为中心;三核;四核;络合物;硫;硒;碲;

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Inverse coordination - An emerging new chemical concept. Oxygen and other chalcogens as coordination centers

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