Lanthanide-based hexa-nuclear complexes and their use as molecular precursors

Calvez Guillaume; Le Natur Francois; Daiguebonne Carole; Bernot Kevin; Suffren Yan; Guillou Olivier

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Lanthanide-based hexa-nuclear complexes and their use as molecular precursors

机译：基于镧系元素的六核配合物及其作为分子前体的用途

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The use of lanthanide-based poly-nuclear complexes as molecular precursor for the design of extended molecular frameworks is still an innovative synthesis strategy. Oxo-hydroxo poly-nuclear complexes are generally obtained by controlling pH conditions during reaction process. After a short description of the lanthanide hydrolysis phenomenon and a non-exhaustive inventory of existing complexes with increasing nuclearity, the present review focuses on lanthanide-based hexa-nuclear oxo-hydroxo complexes. Their syntheses and crystal structures are described and their interest as building blocks for the design of new coordination compounds with unprecedented physical properties is highlighted. (C) 2016 Elsevier B.V. All rights reserved.

机译：基于镧系元素的多核络合物作为分子前体的扩展分子框架设计仍然是一种创新的合成策略。氧-羟基多核络合物通常通过在反应过程中控制pH条件而获得。在对镧系元素水解现象的简短描述和现有的具有越来越高核数的配合物的非详尽清单后，本综述着重于基于镧系元素的六核氧代氢氧配合物。描述了它们的合成和晶体结构，并突出了它们作为设计具有空前物理性质的新配位化合物的基础的兴趣。（C）2016 Elsevier B.V.保留所有权利。

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来源
《Coordination chemistry reviews》 |2017年第6期|134-153|共20页
作者
Calvez Guillaume; Le Natur Francois; Daiguebonne Carole; Bernot Kevin; Suffren Yan; Guillou Olivier;
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作者单位

INSA Rennes, UMR 6226, Inst Sci Chim Rennes, 20 Ave Buttes de Coesmes, F-35708 Rennes, France;

INSA Rennes, UMR 6226, Inst Sci Chim Rennes, 20 Ave Buttes de Coesmes, F-35708 Rennes, France|Olnica SAS, 40 Rue Bignon, F-35135 Chantepie, France;

INSA Rennes, UMR 6226, Inst Sci Chim Rennes, 20 Ave Buttes de Coesmes, F-35708 Rennes, France;

INSA Rennes, UMR 6226, Inst Sci Chim Rennes, 20 Ave Buttes de Coesmes, F-35708 Rennes, France;

INSA Rennes, UMR 6226, Inst Sci Chim Rennes, 20 Ave Buttes de Coesmes, F-35708 Rennes, France;

INSA Rennes, UMR 6226, Inst Sci Chim Rennes, 20 Ave Buttes de Coesmes, F-35708 Rennes, France;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
Hexa-nuclear complexes; Coordination compounds; Molecular precursor; Crystal structures; Photophysical properties;

机译：六核配合物;配位化合物;分子前体;晶体结构;光物理性质;

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1. Lanthanide-based hexanuclear complexes usable as molecular precursors for new hybrid materials [J] . Guillaume Calvez, Carole Daiguebonne, Olivier Guillou Comptes Rendus Chimie . 2010,第6a7期

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6. Models of Molecular Structures of Hexa-Nuclear Al [O] . Oleg V. Mikhailov, Denis V. Chachkov 2021

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7. Lanthanide-based hexa-nuclear complexes and their use as molecular precursors. [O] . Calvez, Guillaume, Le Natur, François, Daiguebonne, Carole, 2017

机译：基于镧系元素的六核配合物及其作为分子前体的用途。

Lanthanide-based hexa-nuclear complexes and their use as molecular precursors

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