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Recent progress on synthesis and structural aspects of rare-earth phosphates

机译:稀土磷酸盐的合成和结构方面的最新进展

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摘要

In this article a brief review of recent progress on preparation and crystal chemistry of rare-earth phosphates have been presented. The article begins with a brief note on the rare-earths and then a description on preparation methods of nano and crystalline samples of binary and complex phosphates. The merits and demerits of the typical procedures are explained in brief. Subsequently the crystal chemistry of various rare-earth phosphates is explained. The diversified crystal chemistry of rare-earth phosphates with compositions as well as with external parameters like pressure and temperature are explained. Typical crystal chemistry of hydrated and anhydrous orthophosphates is also covered. A brief note on phosphates of tetravalent cerium is presented. The high temperature behaviors of complex and metastable phosphates are also discussed. Finally the prospects of rare-earth phosphates for optical and nuclear applications are mentioned in brief. (C) 2017 Elsevier B.V. All rights reserved.
机译:本文简要介绍了稀土磷酸盐的制备和晶体化学的最新进展。本文首先简要介绍了稀土,然后介绍了二元和复杂磷酸盐的纳米和晶体样品的制备方法。简要说明了典型程序的优缺点。随后解释了各种稀土磷酸盐的晶体化学。解释了稀土磷酸盐具有组成以及外部参数(例如压力和温度)的多样化晶体化学。还涵盖了水合和无水正磷酸盐的典型晶体化学。简要介绍了四价铈的磷酸盐。还讨论了复杂和亚稳态磷酸盐的高温行为。最后简要介绍了用于光学和核应用的稀土磷酸盐的前景。 (C)2017 Elsevier B.V.保留所有权利。

著录项

  • 来源
    《Coordination chemistry reviews》 |2017年第6期|266-297|共32页
  • 作者单位

    Bhabha Atom Res Ctr, Div Chem, Mumbai 400085, Maharashtra, India;

  • 收录信息 美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
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