首页> 外文期刊>Coordination chemistry reviews >Carboxylates of rare earth elements
【24h】

Carboxylates of rare earth elements

机译:稀土元素的羧酸盐

获取原文
获取原文并翻译 | 示例
           

摘要

Rare earth carboxylates constitute an enormous group of compounds with various structures and properties. The carboxylate group may be bonded to the metal cations in several ways. The structural aspects of the coordination modes are presented and discussed from the statistical point of view and the most typical groups of carboxylate complexes are reviewed. Data concerning the thermodynamics of formation of the lanthanide, mostly Eu(III), complexes, have been aggregated and briefly analyzed. The electronic spectroscopy of lanthanide carboxylates, mostly focused on analysis of hypersensitive transitions, is discussed for simple carboxylates, acyclic aminopolycarboxylates and dipicolinates, as exemplary systems. (C) 2016 Elsevier B.V. All rights reserved.
机译:稀土羧酸盐构成具有不同结构和性质的大量化合物。羧酸根可以几种方式键合到金属阳离子上。从统计的角度介绍和讨论了配位模式的结构方面,并综述了最典型的羧酸盐配合物基团。关于镧系元素(主要是Eu(III))配合物形成的热力学的数据已经汇总并进行了简要分析。讨论了镧系元素羧酸盐的电子光谱,主要侧重于超敏跃迁的分析,以简单的羧酸盐,无环氨基多羧酸盐和二吡啶甲酸为例进行了讨论。 (C)2016 Elsevier B.V.保留所有权利。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号