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Engineering solid state structural transformations of metal complexes

机译：金属配合物的工程固态结构转变

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Solid state reactivity and structural transformation involving metal complexes driven by nonphotochemical conditions are presented in this review. The single crystals preserved at the end of most of the reactions are discussed. These single-crystal-to-single-crystal ( SCSC) reactions involving bond-breaking and making process by the non-photochemical routes are usually triggered by exposure of solvent vapors and gases, removal or exchange of solvents and guest molecules, heat, or their combinations. The structural transformations of simple metal complexes, metallamacrocycles, organometallic compounds and cages, for example, involve phase transitions accompanied by change in metal-metal bonding distances, change in coordination sphere and geometry, molecular association from monomers and dimers to tetramers and polymers, molecular rearrangements and isomerization, unexpected reactivity that were unknown in solution, and change of chirality. (C) 2017 Elsevier B.V. All rights reserved.
机译：本综述介绍了涉及非光化学条件驱动的金属配合物的固态反应性和结构转变。讨论了大多数反应结束后保存的单晶。这些涉及通过非光化学途径进行的键断裂和制备过程的单晶至单晶（SCSC）反应通常是由溶剂蒸气和气体的暴露，溶剂与客体分子的去除或交换，热或他们的组合。例如，简单金属络合物，金属lamcrocrocycles，有机金属化合物和笼的结构转变涉及相变，伴随着金属-金属键合距离的变化，配位球和几何形状的变化，从单体和二聚体到四聚体和聚合物的分子缔合，分子重排和异构化，溶液中未知的意外反应性以及手性的变化。 （C）2017 Elsevier B.V.保留所有权利。

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