Interacting metal and ligand based open shell systems: Challenges for experiment and theory

Kaim Wolfgang; Paretzki Alexa

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Interacting metal and ligand based open shell systems: Challenges for experiment and theory

机译：基于金属和配体相互作用的开壳系统：实验和理论面临的挑战

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Three-center bridged situations Ru-L-Ru and Q-M-Q (M = Ru, Co, Ni, Cu) containing redox-active transition metals and noninnocently behaving ligand redox systems L-k or Q(n) (o-iminoquinone/o-iminosemiquinone/o-amidophenolate series) can provide valuable insight into electronic and spin interactions of correlated coordination compounds. Experimental approaches using combined structural, electrochemical, spectroscopic (UV-vis-NIR) and magnetic resonance methods were employed with computational support to elucidate which of the potential alternatives are most appropriate to describe the individual electronic structures. (C) 2016 Elsevier B.V. All rights reserved.

机译：三中心桥接情况Ru-L-Ru和QMQ（M = Ru，Co，Ni，Cu）包含氧化还原活性过渡金属并且无害地表现出配体氧化还原体系Lk或Q（n）（邻亚氨基醌/邻亚氨基半醌/邻氨基苯酚酸酯系列）可以提供有关相关配位化合物的电子和自旋相互作用的有价值的见解。使用结合结构，电化学，光谱（UV-vis-NIR）和磁共振方法的实验方法和计算支持，以阐明哪种潜在替代品最适合描述单个电子结构。（C）2016 Elsevier B.V.保留所有权利。

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来源
《Coordination chemistry reviews》 |2017年第8期|345-354|共10页
作者
Kaim Wolfgang; Paretzki Alexa;
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作者单位

Univ Stuttgart, Inst Anorgan Chem, Pfaffenwaldring 55, D-70550 Stuttgart, Germany;

Univ Stuttgart, Inst Anorgan Chem, Pfaffenwaldring 55, D-70550 Stuttgart, Germany;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
Bridged systems; Noninnocent ligands; Oxidation states; Radical ligands; Redox reactions;

机译：桥联体系;非配体;氧化态;自由基配体;氧化还原反应;

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2. Ligand-Unsupported Metal-Metal (M = Cu, Ag) Interactions between Closed-Shell d_10 Trinuclear Systems [J] . Kuljeet Singh, Jeffrey R. Long, Pericles Stavropoulo Journal of the American Chemical Society . 1997,第12期

机译：闭壳d_10三核系统之间配体不受支持的金属（M = Cu，Ag）相互作用
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Interacting metal and ligand based open shell systems: Challenges for experiment and theory

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