Coordination chemistry of the thiosalicylate ligand

Wehr-Candler Tobias; Henderson William

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Coordination chemistry of the thiosalicylate ligand

机译：硫代水杨酸酯配体的配位化学

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Thiosalicylic acid (2-mercaptobenzoic acid, o-HSC6H4CO2H) is an interesting hybrid hard-soft donor ligand, able to coordinate a very wide range of metal centres from the entire periodic table, as either a mono- or di-anion, with a wide range of coordination modes, from simple monodentate through to various bridging modes. This review article summarises the coordination chemistry of the thiosalicylate ligand, with an emphasis on recent developments, especially where X-ray crystallography has been used to provide unequivocal evidence of the binding mode(s) of the thiosalicylate ligand. Applications of the thiosalicylate ligand in materials chemistry are also summarised. (C) 2016 Elsevier B.V. All rights reserved.

机译：硫代水杨酸（2-巯基苯甲酸，o-HSC6H4CO2H）是一种有趣的杂化硬-软供体配体，能够将整个元素周期表中非常广泛的金属中心（单阴离子或双阴离子）与范围广泛的协调模式，从简单的单齿到各种桥接模式。这篇综述文章总结了硫代水杨酸酯配体的配位化学，重点是最近的发展，尤其是在X射线晶体学已被用来提供硫代水杨酸酯配体的结合模式的明确证据的情况下。还概述了硫代水杨酸酯配体在材料化学中的应用。（C）2016 Elsevier B.V.保留所有权利。

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来源
《Coordination chemistry reviews》 |2016年第4期|111-155|共45页
作者
Wehr-Candler Tobias; Henderson William;
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作者单位

Univ Waikato, Sch Sci, Chem, Private Bag 3105, Hamilton 3240, New Zealand;

Univ Waikato, Sch Sci, Chem, Private Bag 3105, Hamilton 3240, New Zealand;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
Thiosalicylate; Thiolate ligand; Carboxylate ligand; Complexes; Structures;

机译：硫代水杨酸酯;硫代酸盐配体;羧酸盐配体;络合物;结构;

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机译：3-和4-巯基苯甲酸酯配体的配位化学：硫代水杨酸酯（2-巯基苯甲酸酯）配体的多功能氢键异构体
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7. Coordination chemistry of 3- and 4-mercaptobenzoate ligands: Versatile hydrogen-bonding isomers of the thiosalicylate (2-mercaptobenzoate) ligand [O] . Tiekink Edward R. T.*, Henderson William 2017

机译：3-和4-巯基苯甲酸酯配体的配位化学：硫代水杨酸酯（2-巯基苯甲酸酯）配体的多功能氢键异构体

Coordination chemistry of the thiosalicylate ligand

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