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首页> 外文期刊>Coordination chemistry reviews >Versatile copper complexes as a convenient springboard for both dyes and redox mediators in dye sensitized solar cells
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Versatile copper complexes as a convenient springboard for both dyes and redox mediators in dye sensitized solar cells

机译：多功能铜络合物可作为染料敏化太阳能电池中染料和氧化还原介体的便捷跳板

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摘要

In the early 1990s, dye-sensitized solar cells (DSSCs), fabricated by O'Regan and Graetzel, emerged as a realistic solution for harnessing the energy of the sun and converting it into electricity. Since then, an impressive amount of work has been carried out in order to improve the global photovoltaic efficiency of DSSCs, trying to optimize every components of the device in terms of material, structure and activity. Up to now, the best efficiencies have been reached with zinc-porphyrin and Ru(II) photosensitizers, but recently an exponential growth of articles showed the great potential of copper(I) coordination compounds as a convenient and cheap alternative. Similarly, it appeared that the use of copper complexes as electron transfer mediators for DSSCs can be an excellent way to solve the problems related to the more common I-3(-)/I- redox couple.
机译：在1990年代初期，由O'Regan和Graetzel制造的染料敏化太阳能电池（DSSC）成为了一种利用太阳能量并将其转化为电能的现实解决方案。从那时起，为了提高DSSC的整体光伏效率，人们进行了大量工作，试图从材料，结构和活性方面优化设备的每个组件。到目前为止，锌卟啉和Ru（II）光敏剂已达到最佳效率，但是最近，指数增长的物品显示出铜（I）配位化合物作为方便和廉价替代品的巨大潜力。同样，看来将铜络合物用作DSSC的电子转移介体可能是解决与更常见的I-3（-）/ I-氧化还原对有关的问题的绝佳方法。

著录项

  • 来源
    《Coordination chemistry reviews》 |2016年第9期|69-93|共25页
  • 作者

    Magni Mirko; Biagini Paolo; Colombo Alessia; Dragonetti Claudia; Roberto Dominique; Valore Adriana;

  • 作者单位

    Univ Milan, Dipartimento Chim, Via Golgi 19, I-20133 Milan, Italy|UdR INSTM, Via Golgi 19, I-20133 Milan, Italy;

    ENI SpA, Ctr Ric Energie Rinnovabili, Via G Fauser 4, I-28100 Novara, Italy|ENI SpA, Ambiente Ist Donegani, Via G Fauser 4, I-28100 Novara, Italy;

    Univ Milan, Dipartimento Chim, Via Golgi 19, I-20133 Milan, Italy|UdR INSTM, Via Golgi 19, I-20133 Milan, Italy;

    Univ Milan, Dipartimento Chim, Via Golgi 19, I-20133 Milan, Italy|UdR INSTM, Via Golgi 19, I-20133 Milan, Italy;

    Univ Milan, Dipartimento Chim, Via Golgi 19, I-20133 Milan, Italy|UdR INSTM, Via Golgi 19, I-20133 Milan, Italy;

    Univ Milan, Dipartimento Chim, Via Golgi 19, I-20133 Milan, Italy|UdR INSTM, Via Golgi 19, I-20133 Milan, Italy;

  • 收录信息 美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Copper complexes; Dye-sensitized solar cells; Photosensitizers; Electron transfer mediators;

    机译：铜络合物;染料敏化太阳能电池;光敏剂;电子转移介体;

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