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首页> 外文期刊>Coordination chemistry reviews >Structural diversity and photoluminescence of copper(I) carboxylates: From discrete complexes to infinite metal-based wires and helices
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Structural diversity and photoluminescence of copper(I) carboxylates: From discrete complexes to infinite metal-based wires and helices

机译：羧酸铜（I）的结构多样性和光致发光：从离散配合物到无限的基于金属的金属丝和螺旋

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摘要

Copper(I) carboxylates have rich photoluminescent properties and broad applications in catalysis, microelectronics, and bioinorganic chemistry. They also exhibit a remarkable structural diversity ranging from discrete complexes to infinite networks based on mono-, di-, tetra-, or hexanuclear copper(I) cores, including unique double-helical arrangements. These structural variations should have important implications on physical and chemical behavior of the resulting crystalline solids, but no structural analysis or structure-property correlations have been established for this family. This work provides the first overview of the types of structures exhibited by crystallographically characterized copper(I) carboxylates having no exogenous ligands, opening pathways for a better understanding of their properties and further advancement of their practical applications. (C) 2015 Elsevier B.V. All rights reserved.
机译：羧酸铜（I）具有丰富的光致发光特性，在催化，微电子学和生物无机化学中具有广泛的应用。它们还表现出显着的结构多样性，从离散复合物到基于单核，二核，四核或六核铜（I）核的无限网络，包括独特的双螺旋结构。这些结构变化应对所得结晶固体的物理和化学行为产生重要影响，但尚未为该族建立结构分析或结构性质相关性。这项工作提供了晶体学特征的不含外源性配体的羧酸铜（I）所展现的结构类型的第一篇综述，为更好地了解其性能和进一步促进其实际应用打开了途径。 （C）2015 Elsevier B.V.保留所有权利。

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