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Approaches for synthesizing breathing MOFs by exploiting dimensional rigidity

机译：利用尺寸刚度合成呼吸MOF的方法

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A subclass of metal-organic frameworks (MOFs) undergoes a "breathing" phenomenon which is a reversible flexing of the framework as a function of adsorbed guest. The existence of multiple stable states in a single framework leads to the modification of the shape and size of the pores as a function of guest, and has encouraged researchers to consider innovative applications for these flexible materials. To assist in improving the designs of these breathing MOFs, a thorough understanding of the different mechanisms by which frameworks breathe, must be established. This review will classify current breathing mechanisms by designating which part of the framework will not flex. By classifying the dimensional rigidity within a framework, a more in-depth discussion of each breathing mechanism can be established. Additionally, strategies for the design and synthesis of the next generation of breathing MOFs based on the reviewed research are discussed.
机译：金属有机骨架（MOF）的子类经历“呼吸”现象，该现象是根据吸附的客体而使骨架发生的可逆弯曲。在单个框架中存在多个稳定状态会导致孔的形状和大小随客体的变化而改变，并鼓励研究人员考虑将这些柔性材料用于创新应用。为了帮助改进这些呼吸MOF的设计，必须建立对框架呼吸的不同机制的透彻理解。这篇综述将通过指定框架的哪一部分不灵活来对当前的呼吸机制进行分类。通过对框架内的尺寸刚度进行分类，可以建立每个呼吸机制的更深入的讨论。另外，还讨论了基于已审查研究的下一代呼吸MOF的设计和合成策略。

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