Novel aspects in the coordination chemistry of mixed group 15/16 cage molecules

Joachim Wachter

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Novel aspects in the coordination chemistry of mixed group 15/16 cage molecules

机译：15/16组混合笼分子的配位化学的新方面

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Cage molecules with mixed group 15 (E = P, As) and group 16 elements (Q=S, Se) are versatile ligands in coordination chemistry. The introduction of solid-state techniques allows one to extend the coordination flexibility of the cage molecules and to realize new coordination modes. The use of P_4S_3 or As_4S_3 as building blocks in copper(I) halide networks has initiated a new kind of "soft" solid-state chemistry, in which solutions of binary inorganic cage molecules are transferred into one-, two- or three-dimensional polymers. This strategy has been stimulated by the existence of competitive phosphorus, arsenic and sulfur coordination sites in the cage molecules.

机译：具有第15组（E = P，As）和第16组元素（Q = S，Se）混合的笼型分子在配位化学中是通用的配体。固态技术的引入使人们能够扩展笼子分子的配位灵活性并实现新的配位模式。使用P_4S_3或As_4S_3作为卤化铜（I）网络的构建基块，引发了一种新型的“软”固态化学，其中将二元无机笼分子的溶液转移为一维，二维或三维聚合物。笼子分子中存在竞争性的磷，砷和硫配位点，从而刺激了这一策略。

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来源
《Coordination chemistry reviews》 |2010年第18期|P.2078-2085|共8页
作者
Joachim Wachter;
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作者单位

Institut fuer Anorganische Chemie der Universitaet Regensburg, Universitaetsstrasse, 93040 Regensburg, Bavaria, Germany;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
pnicogen; chalcogen; coordination polymer; synthesis; crystal structure;

机译：杀虫剂硫属元素配位聚合物合成;晶体结构;

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Novel aspects in the coordination chemistry of mixed group 15/16 cage molecules

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