Coordination complexes incorporating pyrophosphate: Structural overview and exploration of their diverse magnetic, catalytic and biological properties

Oluwatayo F. Ikotun; Nadia Marino; Paul E. Kruger; Miguel Julve; Robert P. Doyle

首页> 外文期刊>Coordination chemistry reviews >Coordination complexes incorporating pyrophosphate: Structural overview and exploration of their diverse magnetic, catalytic and biological properties

【24h】

Coordination complexes incorporating pyrophosphate: Structural overview and exploration of their diverse magnetic, catalytic and biological properties

机译：含焦磷酸盐的配位配合物：结构概述及其各种磁性，催化和生物学性质的探索

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Current attention continues to revolve around the chemistry and biochemistry associated with polyphos-phate anions because of their importance in biology. A pivotal intermediate within this family is the pyrophosphate tetraanion, P_2O_7~(4-). Considering its biological relevance and the multidentate nature that makes it an ideal ligand in the field of the coordination chemistry, there is a growing interest in the use of this anion in building new class of molecules/compounds for different purposes. While the total number of characterized structures still remains modest, several new pyrophosphate-containing coordination complexes have been reported in the last decade, as well as different solid-state structures. This review focuses on the structural, magnetic, and biological properties of coordination complexes incorporating the pyrophosphate ligand reported to date.

机译：由于多磷酸盐阴离子在生物学中的重要性，目前的注意力继续围绕与多磷酸盐阴离子相关的化学和生物化学。该家族中的关键中间体是焦磷酸四阴离子P_2O_7〜（4-）。考虑到其生物学相关性以及使其成为配位化学领域中理想配体的多齿性质，人们越来越关注使用这种阴离子来构建用于不同目的的新型分子/化合物。尽管特征结构的总数仍然很少，但是在过去的十年中，已经报道了几种新的含焦磷酸盐的配位络合物以及不同的固态结构。这项审查侧重于迄今报道的掺入焦磷酸盐配体的配位配合物的结构，磁性和生物学特性。

著录项

来源
《Coordination chemistry reviews》 |2010年第8期|890-915|共26页
作者
Oluwatayo F. Ikotun; Nadia Marino; Paul E. Kruger; Miguel Julve; Robert P. Doyle;
展开▼
作者单位

Department of Chemistry, Syracuse University, Syracuse, NY 13244-4100, USA;

Department of Chemistry, Syracuse University, Syracuse, NY 13244-4100, USA;

Department of Chemistry, College of Science, University of Canterbury, Christchurch, 8020, New Zealand;

Department of Quimica Inorganica/Instituto de Ciencia Molecular, Universitat de Valencia, Poligono La Coma s. E-46980 Paterna. Valencia. Spain;

Department of Chemistry, Syracuse University, Syracuse, NY 13244-4100, USA;

展开▼
收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
pyrophosphate; x-ray crystal structures; magnetism; cytotoxicity; diphosphate;

机译：焦磷酸盐X射线晶体结构;磁;细胞毒性二磷酸;

相似文献

外文文献
中文文献
专利

1. Exploring the biological, catalytic, and magnetic properties of transition metal coordination complexes incorporating pyrophosphate [J] . Greenfield Tiffany J., Julve Miguel, Doyle Robert P. Coordination chemistry reviews . 2019,第APRa期

机译：探索掺入焦磷酸盐的过渡金属配位化合物的生物学，催化和磁性
2. Synthesis and Structural and Magnetic Characterization of {[(phen)2Ni]2(mu-P2O7)} centre dot 27H2O and {[(phen)2Mn]2(mu-P2O7)} centre dot 13H2O:Rare Examples of Coordination Complexes with the Pyrophosphate Ligand [J] . Oluwatayo F.Ikotun, N.Gabriel Armatus, Miguel Julve Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2007,第16期

机译：{[（phen）2Ni] 2（mu-P2O7）}中心点27H2O和{[（phen）2Mn] 2（mu-P2O7）}中心点13H2O的合成，结构和磁性表征：带有焦磷酸盐配体
3. Correction:Self-assembly ofmixed-valence Co(II/III) and Ni(II) clusters: azide-bridged 1D single chain coordination polymers comprised of tetranuclear units, tetranuclear Co(II/III) complexes, ferromagnetically coupled azide-bridged tetranuclear, and hexanuclear Ni(II) complexes: synthesis, structural, and magnetic properties (pg 6536, 2010) [J] . Tandon SS, Bunge SD, Rakosi R, Dalton transactions: An international journal of inorganic chemistry . 2010,第47期

机译：校正：混合价Co（II / III）和Ni（II）簇的自组装：叠氮桥联的一维单链配位聚合物，由四核单元，四核Co（II / III）络合物，铁磁耦合的叠氮化物桥联的四核，和六核Ni（II）配合物：合成，结构和磁性能（pg 6536，2010）
4. STRUCTURAL AND REDOX PROPERTIES OF VANADIUM COMPLEXES IN MOLTEN SALTS OF INTEREST FOR THE CATALYTIC OXIDATION OF SULFUR DIOXIDE [C] . Soghomon Boghosian, Athanassios Chrissanthopoulos, Rasmus Fehrmann Twelfth International Symposium on Molten Salts, 12th, Oct 17-22, 1999, Honolulu Hawaii . 1999

机译：有趣的熔融盐中钒络合物的结构和氧化还原特性对二氧化硫的催化氧化
5. Investigating the pharmacodynamic and magnetic properties of pyrophosphate-bridged coordination complexes. [D] . Ikotun, Oluwatayo (Tayo) F. 2009

机译：研究焦磷酸桥联配位化合物的药效和磁性。
6. Comparison of Structurally–Related Alkoxide Amine and Thiolate–Ligated MII (M= Fe Co) Complexes: the Influence of Thiolates on the Properties of Biologically Relevant Metal Complexes [O] . Lisa M. Brines, Gloria Villar-Acevedo, Terutaka Kitagawa, -1

机译：结构相关的醇盐胺和硫醇盐连接的MII（M = FeCo）配合物的比较：硫醇盐对生物相关金属配合物性能的影响
7. Synthesis and Structural and Magnetic Characterization of {(phen)2Ni2(m-P2O7)}27H2O and {(phen)2Mn2(m-P2O7)}13H2O: Rare Examples of Coordination Complexes with the Pyrophosphate Ligand [O] . -1

机译：{（Phen）2Ni 2（M-P2O7）} 27H2O和{（Phen）2Mn 2（M-P2O7）} 2（M-P2O7）} 13H2O：用焦磷酸盐配体的配位复合物的罕见实施例

Coordination complexes incorporating pyrophosphate: Structural overview and exploration of their diverse magnetic, catalytic and biological properties

摘要

著录项

相似文献

相关主题

期刊订阅