Structures and properties of gold(I) complexes of interest in biochemical applications

Hanan E. Abdou; Ahmed A. Mohamed; John P. Fackler Jr.; Alfredo Burini; Rossana Galassi; Jose M. Lopez-de-Luzuriaga; M. Elena Olmos

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Structures and properties of gold(I) complexes of interest in biochemical applications

机译：生化应用中感兴趣的金（I）配合物的结构和性质

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Gold(I) compounds have several potential roles in biologically related chemistry. The relatively low tox-icity of gold and its lability allows human consumption of drugs formed with this element. Trinuclear and tetranuclear clusters look particularly interesting because of the strong basicity of the gold(I) centers in these molecules. Future studies are expected to lead to interesting new bio-related observations. The ability of gold(I) compounds to interact with themselves aurophilically and with other heavy element ions has produced spectroscopic properties which are sensitive to volatile organic compounds (VOCs) and other molecular interactions. Thus bio-applicability for sensing toxic components appears reasonable.

机译：金（I）化合物在生物相关化学中具有多种潜在作用。黄金相对较低的毒性及其不稳定性使得人类可以食用由这种元素形成的药物。三核和四核簇看起来特别有趣，因为这些分子中的金（I）中心具有很强的碱性。预期未来的研究将导致有趣的新的生物相关观察。金（I）化合物与自身和其他重元素离子发生相互作用的能力产生了对挥发性有机化合物（VOC）和其他分子相互作用敏感的光谱性质。因此，用于感测有毒成分的生物适用性似乎是合理的。

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来源
《Coordination chemistry reviews》 |2009年第12期|1661-1669|共9页
作者
Hanan E. Abdou; Ahmed A. Mohamed; John P. Fackler Jr.; Alfredo Burini; Rossana Galassi; Jose M. Lopez-de-Luzuriaga; M. Elena Olmos;
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作者单位

Department of Chemistry and Laboratory for Molecular Structure and Bonding, Texas A&M University, P.O. Box 30012, College Station. TX 77842-3012, USA;

Department of Chemistry and Laboratory for Molecular Structure and Bonding, Texas A&M University, P.O. Box 30012, College Station. TX 77842-3012, USA;

Department of Chemistry and Laboratory for Molecular Structure and Bonding, Texas A&M University, P.O. Box 30012, College Station. TX 77842-3012, USA;

Dipartimento di Scienze Chimiche dell' Universita via S. Agostino 1,1-62032 Camerino, Italy;

Dipartimento di Scienze Chimiche dell' Universita via S. Agostino 1,1-62032 Camerino, Italy;

Departamento de Quimica, Universidad de La Rioja, Grupo de Sintesis Quimica de La Rioja, UA-CSIC, Madre de Dios 51. E-26004 Logrono, Spain;

Departamento de Quimica, Universidad de La Rioja, Grupo de Sintesis Quimica de La Rioja, UA-CSIC, Madre de Dios 51. E-26004 Logrono, Spain;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
gold(I); thiolates; amidinates; ylides; carbeniates; pyrazolates; luminescence; sensors;

机译：金（I）;硫醇盐mid叶利德碳酸盐吡唑酸盐发光感应器;

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Structures and properties of gold(I) complexes of interest in biochemical applications

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