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Preface

机译:前言

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摘要

Although they had no idea of what an amphiphilic molecule or a micelle was, humans exploited the ability of micelles to include lipophilic molecules in their hydrophobic core since the discovery of soap, which dates back at least to 2800 BC. Surfactant science has developed enormously since then, and particularly in the 20th century, when the detergent industry expanded rapidly and the process of solubilization of hydrophobic molecules in micel-lar aqueous solutions was rationalized. With the late 60s, micellar chemistry received a strong impulse with the development of the concept that micellar aggregates may be models for biological membranes. Ten years later, attention was amplified by the mounting wave of supramolecular chemistry. A micelle is intrinsically a supermolecule, and it was soon realized that self-assembling a huge number of molecular units in the same supramolecular entity may bring many advantages, e.g. as regards cooperativity and catalysis.
机译:尽管他们不知道什么是两亲性分子或胶束,但是自发现肥皂以来,人类就利用了胶束将亲脂性分子包括在疏水核中的能力,这种肥皂的历史至少可以追溯到公元前2800年。此后,特别是在20世纪,表面活性剂科学取得了长足的发展,这是因为洗涤剂行业迅速发展,并且使胶束状水溶液中疏水性分子的溶解过程得到合理化。在60年代后期,随着胶束聚集体可能是生物膜模型的概念的发展,胶束化学受到了强烈的推动。十年后,超分子化学的迅猛发展引起了人们的关注。胶束本质上是一种超分子,不久就意识到,在同一超分子实体中自组装大量分子单元可能带来许多优势,例如,关于合作性和催化作用。

著录项

  • 来源
    《Coordination chemistry reviews》 |2009年第18期|2131-2132|共2页
  • 作者

    Piersandro Pallavicini;

  • 作者单位

    Dipartimento di Chimica Generate, Universita di Pavia, viale Taramelli, 12, 27100 Pavia, Italy;

  • 收录信息 美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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