Dinuclear and polynuclear lanthanide coordination complexes containing polyazine ligands: Synthesis and luminescent properties

Shawn Swavey; Rochael Swavey

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Dinuclear and polynuclear lanthanide coordination complexes containing polyazine ligands: Synthesis and luminescent properties

机译：含聚嗪配体的双核和多核镧系配位化合物：合成和发光性能

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The role of homodinuclear and heterodinuclear lanthanide complexes as building blocks for polymeric materials is a significant field of study in recent years. Accessing the desired luminescent properties of lanthanides in the most efficient and practical way is an important part of designing such complex structures. This review describes the background of the photophysical properties of a select number of lanthanide ions. The synthesis and photophysical properties of dinuclear lanthanides have been split into two sections: (ⅰ) heterdinuclear d-f complexes and (ⅱ) homodinuclear lanthanides bridged by polyazine ligands. A section on polymeric lanthanide arrays is also included highlighting d-f polymeric structures and a section on homodinuclear polymeric arrays formed from polyazine bridging ligands.

机译：近年来，同核和异核镧系元素络合物作为聚合物材料的基础材料的作用是一个重要的研究领域。以最有效和最实用的方式获得镧系元素的所需发光特性是设计此类复杂结构的重要组成部分。这篇综述描述了一定数量的镧系离子的光物理性质的背景。双核镧系元素的合成和光物理性质已分为两部分：（ⅰ）杂核d-f配合物和（ⅱ）聚嗪配体桥接的同核镧系元素。关于聚合物镧系元素阵列的部分也包括突出显示的d-f聚合物结构，以及关于由聚嗪桥联配体形成的同核聚合物阵列的部分。

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来源
《Coordination chemistry reviews》 |2009年第22期|2627-2638|共12页
作者
Shawn Swavey; Rochael Swavey;
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作者单位

Department of Chemistry, University of Dayton, Dayton, OH 45469-2357, USA;

Department of Chemistry, University of Dayton, Dayton, OH 45469-2357, USA;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
polyazine; polymeric array; homodinuclear; lanthanide;

机译：聚嗪聚合物阵列同核镧系元素;

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Dinuclear and polynuclear lanthanide coordination complexes containing polyazine ligands: Synthesis and luminescent properties

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