Engineering of molecular architectures of β-diketonate precursors toward new advanced materials

Guglielmo G. Condorelli; Graziella Malandrino; Ignazio L. Fragala

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Engineering of molecular architectures of β-diketonate precursors toward new advanced materials

机译：β-二酮酸酯前体的分子结构对新型先进材料的工程设计

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Metal complexes bearing linked hexafluoroacetylacetonates and ancillary Lewis ligands, have found wide interest as precursors for metal-organic chemical vapor deposition (MOCVD) since their first description in 1991. The relationships involving their molecular architectures, mass transport properties, decomposition mechanisms of both alkaline- and rare-earth metal precursors are compared to fluorine-free β-diketonates. The perspectives of applications to MOCVD processes of a large range of advanced materials in thin film forms are discussed in detail. The effects due to the nature of the β-diketonate moiety as well as of the ancillary ligand on mentioned properties are discussed in detail.

机译：自1991年首次描述以来，带有连接的六氟乙酰丙酮化物和辅助Lewis配体的金属络合物作为金属有机化学气相沉积（MOCVD）的前体已引起广泛关注。这些关系涉及它们的分子结构，质量传输性质，碱金属和金属的分解机理将稀土金属前体与不含氟的β-二酮酸盐进行了比较。详细讨论了薄膜形式的各种先进材料在MOCVD工艺中的应用前景。详细讨论了由于β-二酮酸部分以及辅助配体的性质对上述性质的影响。

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来源
《Coordination chemistry reviews》 |2007年第14期|p.1931-1950|共20页
作者
Guglielmo G. Condorelli; Graziella Malandrino; Ignazio L. Fragala;
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作者单位

Dipartimento di Scienze Chimiche, Universita di Catania, and INSTM, UdR Catania, Viale A. Doria 6, I-95125 Catania, Italy;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
MOCVD; alkaline-earth; rare-earth; adducts; decomposition mechanisms; thin films;

机译：MOCVD;碱土;稀土;加合物;分解机理;薄膜;

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1. Volatile metal beta-diketonates - new precursors for the sonochemical synthesis of nanosized materials - sonolysis of thorium(IV) beta-diketonates [J] . Nikitenko SI., Tcharushnikova IA., Blanc P., Ultrasonics sonochemistry . 2000,第4期

机译：挥发性金属β-二酮-超声化学合成纳米材料的新前体-β-二酮ike的声解
2. Volatile metal β-diketonates -- new precursors for the sonochemical synthesis of nanosized materials -- sonolysis of thorium (IV) β-diketonates [J] . S. I. Nikitenko, Ph. Moisy, I. A. Tcharushnikova, Ultrasonics sonochemistry . 2000,第4期

机译：挥发性金属β-二酮-超声化学合成纳米材料的新前体-β（IV）β-二酮的声解
3. Volatile metal β-diketonates—new precursors for the sonochemical synthesis of nanosized materials—sonolysis of thorium(IV) β-diketonates [J] . S.I. Nikitenko, Ph. Moisy, I.A. Tcharushnikova Ultrasonics . 2000,第4期

机译：挥发性金属β-二酮盐—纳米材料声化学合成的新前体— IV（IV）β-二酮盐的超声分解
4. Barium bis(#beta#-Diketonate) centre dot tetraglyme Complexes as Potential CVD Precursors for Electronic Materials [C] . Henry A. Luten III, David J. Otway, William S. Rees Metal-Organic Chemical Vapor Deposition of Electronic Ceramics Meeting . 1997

机译：BIS BIS（＃Beta＃-dikeTonate）中心点Tetraglyme复合物作为电子材料的潜在CVD前体
5. Heterometallic beta-diketonates and oxo-diketonates as single source precursors for the synthesis of oxide materials. [D] . Zhang, Haitao. 2010

机译：异金属β-二酮酸酯和氧-二酮酸酯作为合成氧化物材料的单一来源前体。
6. Two-Dimensional Transition Metal Oxide and Hydroxide-Based Hierarchical Architectures for Advanced Supercapacitor Materials [O] . Meili Guan, Qiuwan Wang, Xuan Zhang, 2020

机译：基于二维过渡金属氧化物和氢氧化物的高级超级电容器材料的分层体系结构
7. Molecular Engineering of MnII Diamine Diketonate Precursors for the Vapor Deposition of Manganese Oxide Nanostructures [O] . Chiara Maccato, Lorenzo Bigiani, Giorgio Carraro, 2017

机译：MnII二胺的分子工程掺酮氧化锰纳米结构的气相沉积前体

Engineering of molecular architectures of β-diketonate precursors toward new advanced materials

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