Ephedrine derivatives, extraordinary tools for the study of stereogenic centers in tetra- to heptacoordinated complexes

Rosalinda Contreras; Angelina Flores-Parra; Horacio C. Lopez-Sandoval; Norah Barba-Behrens

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Ephedrine derivatives, extraordinary tools for the study of stereogenic centers in tetra- to heptacoordinated complexes

机译：麻黄碱衍生物，用于研究四至七配位复合物立体中心的非凡工具

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We have been investigating the synthesis of diverse ephedrine derivatives, as polyfunctional ligands, heterocyclic compounds, and metal and metalloid complexes. In this review, we present a brief discussion of our experience and from other research groups concerning the creation of stereogenic centers, different from carbon, in diverse ephedrine based molecules.

机译：我们一直在研究各种麻黄碱衍生物的合成，如多官能团配体，杂环化合物以及金属和准金属络合物。在这篇综述中，我们简要介绍了我们的经验以及来自其他研究小组的关于在多种基于麻黄碱的分子中创建不同于碳的立体异构中心的经验。

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来源
《Coordination chemistry reviews》 |2007年第14期|p.1852-1867|共16页
作者
Rosalinda Contreras; Angelina Flores-Parra; Horacio C. Lopez-Sandoval; Norah Barba-Behrens;
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作者单位

Departamento de Quimica, Cinvestav, A.P. 14-740, Mexico 07000, DF, Mexico;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
stereochemistry; stereogenic centers; ephedrine derivatives; phosphorous; boron; transition metals; coordination compounds;

机译：立体化学;立体异构中心;麻黄碱衍生物;磷;硼;过渡金属;配位化合物;

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机译：两种含有2,9-二甲基-1,10-菲咯啉（phen），硝酸根和烟碱的七配位Mn（II）配合物的XRD结构：[Mn（phen）（nicot）（NO3）（H2O）]中心点EtOH中心点H2O和[Mn（phen）（NO3）（2）（H2O）]
2. A study toward understanding the role of a phosphorus stereogenic center in (5S)-1,3-diaza-2-phospha-2-oxo-3-phenylbicyclo(3.3.0)octane derivatives as catalysts in the borane-mediated asymmetric reduction of prochiral ketones [J] . Basavaiah D, Chandrashekar V, Das U, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2005,第24期

机译：旨在理解磷立体异构中心在（5S）-1,3-二氮杂-2-磷酸-2-氧代-3-苯基双环（3.3.0）辛烷衍生物作为硼烷介导的不对称还原反应中的催化剂的作用的研究前手性酮
3. New Heptacoordinated Organotin(IV) Complexes Derivatives of 2,6-diacetylpyridinebis(2-furanoylhydrazone), H2dapf, and 2,6-diacetylpyridinebis(2-thenoylhydrazone), H2dapt: Crystal and Molecular Structure of [Me2Sn(Hdapt]Br.H2O [J] . Ana M.g.d. Rodrigues, Anuar Abras, Gerimário F. De Sousa, Journal of the Brazilian Chemical Society . 1999,第3期

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4. Synthesis of Rhodium Allyl Complexes Having a Stereogenic Center on the Metal Center [C] . Yasutaka Kataoka, Takahiro Akashi, Tsuneaki Yamagata, Symposium on Organometallic Chemistry . 2004

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7. Induced-fit recognition of DNA by organometallic complexes with dynamic stereogenic centers [O] . Chen, Haimei, Parkinson, John A., Nováková, Olga, 2003

机译：具有动态立体中心的有机金属配合物对DNA的诱导拟合识别

Ephedrine derivatives, extraordinary tools for the study of stereogenic centers in tetra- to heptacoordinated complexes

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