Coordination design of artificial metalloproteins utilizing protein vacant space

Takafumi Ueno; Satoshi Abe; Norihiko Yokoi; Yoshihito Watanabe

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Coordination design of artificial metalloproteins utilizing protein vacant space

机译：利用蛋白质空位的人工金属蛋白配合设计

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Design of artificial metalloproteins is one of the most important subjects in the field of bioinorganic chemistry. In order to prepare them, vacant space of proteins has been utilized because it gives us unique chemical environment to construct catalysts and materials. This article reviews on preparation methods and properties of metal/protein composites. The discussion includes our recent results and development in the screening of composites, crystal structures, molecular design of bio-inspired systems concerning catalysts, electrochemistry, and materials.

机译：人工金属蛋白的设计是生物无机化学领域中最重要的主题之一。为了制备它们，利用了蛋白质的空位，因为它为我们提供了独特的化学环境来构建催化剂和材料。本文综述了金属/蛋白质复合材料的制备方法和性能。讨论内容包括我们在复合材料的筛选，晶体结构，与催化剂，电化学和材料有关的生物启发系统的分子设计方面的最新成果和进展。

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来源
《Coordination chemistry reviews》 |2007年第24期|2717-2731|共15页
作者
Takafumi Ueno; Satoshi Abe; Norihiko Yokoi; Yoshihito Watanabe;
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作者单位

Department of Chemistry, Graduate School of Science, Nagoya University, Nagoya 464-8602, Japan;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
myoglobin; ferritin; nanoparticle; biomineralization; metalloenzyme; heme;

机译：肌红蛋白铁蛋白纳米粒子生物矿化;金属酶血红素;

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专利

1. Design and structure analysis of artificial metalloproteins: Selective coordination of his64 to copper complexes with square-planar structure in the apo-myoglobin scaffold [J] . Abe S, Ueno T, Reddy PAN, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2007,第13期

机译：人工金属蛋白的设计与结构分析：载脂蛋白-肌红蛋白支架中his64与方形结构的铜配合物的选择性配位
2. USE OF LIGAND DESIGN TO PROVIDE COORDINATION ASYMMETRY IN A BINUCLEAR METALLOPROTEIN MODEL SYSTEM - LIGAND SYNTHESIS, COORDINATION CHEMISTRY WITH COPPER, AND DEMONSTRATION OF SITE-DIRECTED REACTIVITY [J] . Satcher JH., Weakley TJR., Taylor RT., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1995,第12期

机译：利用配体设计在双核金属蛋白模型系统中提供配位不对称性-配体合成，铜的配位化学和现场定向反应性的证明
3. USE OF LIGAND DESIGN TO PROVIDE COORDINATION ASYMMETRY IN A BINUCLEAR METALLOPROTEIN MODEL SYSTEM - LIGAND SYNTHESIS, COORDINATION CHEMISTRY WITH COPPER, AND DEMONSTRATION OF SITE-DIRECTED REACTIVITY [J] . Satcher JH., Weakley TJR., Taylor RT., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1995,第12期

机译：利用配体设计在双核金属蛋白模型系统中提供配位不对称性-配体合成，铜的配位化学和现场定向反应性的证明
4. FROM NATURAL TO ARTIFICIAL METALLOPROTEINS - CHALLENGES AND OPPORTUNITIES [C] . Johannes Schiffels, Daniel F. Sauer, Jun Okuda, Conference on biochemical and molecular engineering . 2019

机译：从天然金属蛋白到人工金属蛋白-挑战与机遇
5. Using coordination chemistry concepts for computational metalloprotein design. [D] . Shete, Vivekanand S. 2007

机译：使用配位化学概念进行金属蛋白设计计算。
6. Noncoded Amino Acids in de Novo Metalloprotein Design: Controlling Coordination Number and Catalysis [O] . Karl J. Koebke, Vincent L. Pecoraro -1

机译：新生金属蛋白设计中的非编码氨基酸：控制配位数和催化
7. Design and Structure Analysis of Artificial Metalloproteins: Selective Coordination of His64 to Copper Complexes with Square-Planar Structure in the apo-Myoglobin Scaffold [O] . -1

机译：人工金属蛋白的设计与结构分析：Apo-Myoglobin支架中方形平面结构与铜络合物的选择性协调

Coordination design of artificial metalloproteins utilizing protein vacant space

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