Advanced design of catalytically active reaction space at surfaces for selective catalysis

Mizuki Tada; Yasuhiro Iwasawa

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Advanced design of catalytically active reaction space at surfaces for selective catalysis

机译：用于选择性催化的表面催化活性反应空间的高级设计

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The recent advanced design of surface reaction spaces for heterogeneous selective catalysis in molecular-nano scales is reviewed, focusing on our recent challenges and also presenting new data. Supported metal complexes on oxide surfaces often exhibit tremendous catalytic properties based on their unique coordination structures created at the surfaces. Novel active reaction spaces can be designed by coordination regulation on central metals, chemical interaction at metal-surface interface, and three-dimensional architectures constructed at surfaces. Such molecularly organized surfaces possess advantageous properties of both homogeneous and heterogeneous catalyst systems and provide great opportunities for the tailor-made design of highly selective catalysis for various kinds of catalytic chemical syntheses.

机译：本文综述了分子纳米尺度上用于非均相选择性催化的表面反应空间的最新设计，重点关注了我们最近面临的挑战，并提出了新的数据。氧化物表面的负载金属络合物通常会基于其在表面形成的独特配位结构而展现出巨大的催化性能。可以通过对中心金属的配位调节，在金属-表面界面的化学相互作用以及在表面构造的三维结构来设计新型的活性反应空间。这种分子组织的表面具有均相和非均相催化剂体系的有利性质，并且为针对各种催化化学合成的高选择性催化的定制设计提供了巨大的机会。

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来源
《Coordination chemistry reviews》 |2007年第24期|2702-2716|共15页
作者
Mizuki Tada; Yasuhiro Iwasawa;
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作者单位

Department of Chemistry, Graduate School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
supported metal complex; catalyst surface; heterogeneous catalyst; chemical design; active structure; molecular imprinting; chiral self-assembly; asymmetric catalysis; oxidative coupling; selective oxidation; hydrogenation; characterization;

机译：支撑金属配合物;催化剂表面非均相催化剂化学设计;活动结构;分子印迹手性自组装;不对称催化氧化偶合选择性氧化;氢化;表征;

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1. Surface-mediated design and catalytic properties of active metal complexes for advanced catalysis creation [J] . Tada M. Bulletin of the Chemical Society of Japan . 2010,第8期

机译：用于高级催化创建的活性金属配合物的表面介导设计和催化性能
2. Surface-mediated design and catalytic properties of active metal complexes for advanced catalysis creation [J] . Tada M. Bulletin of the Chemical Society of Japan . 2010,第8期

机译：用于高级催化创建的活性金属配合物的表面介导设计和催化性能
3. The catalytic activity of space versus terrestrial synthesized zeolite Beta catalysts in the Meerwein Ponndorf Verley Reactions: Support for PFAL as the Lewis active site for cis-alcohol selectivity [J] . Burcu Akata, Trevor L. Goodrich, Katherine S. Ziemer, Microgravity science and technology . 2007,第2期

机译：Meerwein Ponndorf Verley反应中空间对地面合成沸石Beta催化剂的催化活性：支持PFAL作为路易斯醇对顺式醇选择性的活性位点
4. Nanopore-governed heterogeneous catalysis: designing selective reaction cavities on metal surfaces [C] . Chia-Kuang Tsung ACS National Meeting Exhibition . 2013

机译：纳米孔治理的异质催化：在金属表面上设计选择性反应腔
5. Controlling the Three-Dimensional Environment of Catalytic Active Sites for Selective Heterogeneous Catalysis [D] . Wang, Bingwen . 2019

机译：控制催化活性位点的三维环境，用于选择性异质催化
6. Structure of chymopapain M the late-eluted chymopapain deduced by comparative modelling techniques and active-centre characteristics determined by pH-dependent kinetics of catalysis and reactions with time-dependent inhibitors: the Cys-25/His-159 ion-pair is insufficient for catalytic competence in both chymopapain M and papain. [O] . M P Thomas, C M Topham, D Kowlessur, 1994

机译：通过比较建模技术推导的乳糜蛋白酶M的结构为晚期洗脱的乳糜蛋白酶其活性中心特征由pH依赖的催化动力学和与时间依赖性抑制剂的反应确定：Cys-25 / His-159离子对不足以催化糜蛋白酶M和木瓜蛋白酶的能力。
7. Frontiers of Photo-catalysis and Photo-reaction at Solid Surfaces. Design and Development of a Titanium Oxide Photocatalyst Able to Work Effectively under Visible Light Irradiation by an Advanced Metal Ion-Implantation Method. [O] . Masakazu ANPO, Masato TAKEUCHI, Satoru KISHIGUCHI, 1999

机译：固体表面的光催化和光反应的边缘。通过先进的金属离子注入方法在可见光照射下有效地工作的氧化钛光催化剂的设计和开发。
8. Contribution of Surface Catalysis and Gas Phase Reaction to Catalytic Combustor Performance [R] . Ablow, C. M., Schechter, S., Wise, H., 1979

机译：表面催化和气相反应对催化燃烧器性能的贡献

Advanced design of catalytically active reaction space at surfaces for selective catalysis

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