Supramolecular chemistry and complexation abilities of diphosphonic acids

Ewa Matczak-Jon; Veneta Videnova-Adrabinska

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Supramolecular chemistry and complexation abilities of diphosphonic acids

机译：二膦酸的超分子化学和络合能力

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The solution and solid state complexation features for two classes of diphosphonic acids: with gem-phosphonic-phosphonate groups or with a C—N—C spacer between them are reviewed. In particular, the co-ordination and the Supramolecular networks in their complexes are discussed. The structural analysis revealed a large variety of coordination units, dependent upon the topochemical nature of the ligands, the geometrical and charge preferences of the metal ions, and the influence of the counter ions. An amazing superstructural and Supramolecular diversity is observed in the extended frameworks. The solution-solid state relationships are elucidated and the role of the hydrogen bonds for the metal complexation in solution is also revealed.

机译：回顾了两类二膦酸的溶液和固态络合特征：具有双膦酸酯基膦酸酯基或它们之间具有C-NC间隔基。特别地，讨论了它们的配合物中的配位和超分子网络。结构分析表明，取决于配体的拓扑化学性质，金属离子的几何形状和电荷偏好以及抗衡离子的影响，配位单元种类繁多。在扩展框架中观察到了惊人的超结构和超分子多样性。阐明了溶液与固态之间的关系，并揭示了氢键在溶液中金属络合中的作用。

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来源
《Coordination chemistry reviews》 |2005年第22期|p.2458-2488|共31页
作者
Ewa Matczak-Jon; Veneta Videnova-Adrabinska;
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作者单位

Department of Chemistry, Wroclaw University of Technology, Wybrzeze Wyspianskego 27, 50-370 Wroclaw, Poland;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
diphosphonic acid; complexation capabilities; coordination networks;

机译：二膦酸络合能力配位网络;

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1. Ethane-1,2-diphosphonic acid as a building block in supramolecular chemistry; a pillared-layer framework and framework-encapsulated cations [J] . Wheatley PS., Ferguson G., Burchell CJ., Acta Crystallographica, Section B. Structural Science . 2001,第1期

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2. Synthesis of N-methyl alkylaminomethane-1,1-diphosphonic acids and evaluation of their complex-formation abilities towards copper(II) [J] . Kurzak Barbara, Goldeman Waldemar, Szpak Magdalena, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2015,第Null期

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3. Role of the Side Chain Modifications for the Solution Behavior and the Complex-Forming Abilities of Some Aminomethane-l,l-diphosphonic Acids.Relevance to Biological Activity [J] . E.Matczak-Jon Polish Journal of Chemistry . 2005,第3期

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4. Supramolecular Complexes of Humic Acids Including Complexation of Nano-particles. Spectrophotometric, Spectrofluorimetric, Capillary Electrophoretic and Mass Spectrometric Study [C] . Josef Havel, Eladia M. Pena-Mendez International Meeting of the International Humic Substances Society . 2010

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5. Chemistry and supramolecular chemistry of the iota-amino acid aminodiphenylmethanecarboxylic acid (Adc) and its derivatives. [D] . Kang, Sang-Woo. 2008

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7. Copper Electrodeposition from Non-Cyanide Alkaline Baths Containing Methylene Diphosphonic Acid as a Complexing Agent [O] . ZHENG Jing-Wu, LU Guo-Ying, QIAO Liang, 2011

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8. SANS study of dialkylsubstituted diphosphonic acids and their complexes with Ca, Fe, La, Th and U in toluene [R] . Urban, V. , Ku, C. Y. , Thiyagarajan, P. 1997

机译：saNs研究二烷基取代二膦酸及其与甲苯中Ca，Fe，La，Th和U的配合物

Supramolecular chemistry and complexation abilities of diphosphonic acids

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