Biheteroaromatic diphosphines and their transition metal complexes: synthesis, characterisation and applications in asymmetric catalysis

Terry T.-L. Au-Yeung; Albert S.C. Chan

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Biheteroaromatic diphosphines and their transition metal complexes: synthesis, characterisation and applications in asymmetric catalysis

机译：双杂芳族二膦及其过渡金属配合物：合成，表征和在不对称催化中的应用。

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Chelating diphosphines supported by biheteroaromatic compounds find increasing application in metal-catalyzed homogeneous catalysis. This review describes recent development in the synthesis and characterisation of atropisomeric biheteroaromatic diphosphines and some of their metal complexes by spectroscopic methods. The applications of the diphosphines in the asyttimetric hydrogenation of α-, β-amino acid precursors and ketones, 1,4-arylation of enones, bis-alkoxycarbonylation, Heck reaction and Diels-Alder reaction are also discussed.

机译：由双杂芳族化合物负载的螯合二膦在金属催化的均相催化中发现越来越多的应用。这篇综述描述了通过光谱学方法合成和表征阻转异构的双杂芳族二膦及其金属配合物的最新进展。还讨论了二膦在α-，β-氨基酸前体和酮的不规则氢化中的应用，烯酮的1,4-芳基化，双烷氧基羰基化，Heck反应和Diels-Alder反应的应用。

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来源
《Coordination chemistry reviews》 |2004年第24期|p.2151-2164|共14页
作者
Terry T.-L. Au-Yeung; Albert S.C. Chan;
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作者单位

Open Laboratory of Chirotechnology of the Institute of Molecular Technology for Drug Discovery and Synthesis and Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Kong;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
biheteroaromatic diphosphines; axial chirality; asymmetric hydrogenation; asymmetric 1; 4-addition; bis-alkoxycarbonylation; asymmetric heck reaction; asymmetric diels-alder reaction;

机译：双杂芳族二膦;轴向手性;不对称氢化;不对称1;4-加成;双烷氧基羰基化;不对称heck反应;不对称diels-alder反应;

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1. Transition metal complexes with the C-1-symmetric diphosphines (R)-(R)-3-benzyl-2,4-bis(diphenylphosphino)pentane and (R)-(R)-3-benzyl(p-sulphonate)-2,4-bis(diphenylphosphino)pentane sodium salt. Applications to enantioselective catalysis in differen [J] . Bianchini C., Scapacci G., Barbaro P. Journal of Organometallic Chemistry . 2001,第1a2期

机译：与C-1-对称二膦（R）-（R）-3-苄基-2,4-双（二苯基膦基）戊烷和（R）-（R）-3-苄基（对磺酸酯）-的过渡金属配合物2,4-双（二苯基膦基）戊烷钠盐。在不同对映体选择性催化中的应用
2. Synthesis Catalytic Application of Several d8 Transition Metal Diphosphine Complexes, MCl2PP (M = Ni2+, Pd2+, Pt2+, Au3+ ; PP = diphosphines) [J] . Kyung-Chae Kim, Young-Jae Cho, Yu-Chul Park Journal of the Korean Chemical Society . 1992,第5期

机译：几种d8过渡金属二膦配合物MCl2PP的合成催化应用（M = Ni2 +，Pd2 +，Pt2 +，Au3 +; PP =二膦酸酯）
3. Enantioselective Synthesis of Planar-Chiral Transition-Metal Complexes by Homogeneous Olefi n-Metathesis Reactions and Their Application in Asymmetric Catalysis [J] . 小笠原正道 Bulletin of Japan Society of Coordination Chemistry . 2017,第3期

机译：均相烯烃置换反应对手性过渡金属配合物的对映选择性合成及其在不对称催化中的应用
4. Heterobimetallic Transition Metal-Rare Earth Metal-Schiff Base Complexes and Applications to Bifunctional Asymmetric Catalysis [C] . Shigeki Matsunaga, Shinya Handa, Zhihua Chen Symposium on Organometallic Chemistry . 2007

机译：异质过渡金属 - 稀土金属 - 席克夏料复合物和应用于双官能的不对称催化
5. Synthesis of gold complexes from diphosphine ligands and screening reactions of heterocyclic acetylacetonato (ACAC) ligands with transitional metal complexes. [D] . Nyamwihura, Rogers. 2015

机译：由二膦配体合成金配合物，以及杂环乙酰丙酮基（ACAC）配体与过渡金属配合物的筛选反应。
6. Asymmetric Catalysis Special Feature Part II: Remarkably diastereoselective synthesis of a chiral biphenyl diphosphine ligand and its application in asymmetric hydrogenation [O] . Liqin Qiu, Jing Wu, Shusun Chan, 2004

机译：不对称催化特征第二部分：手性联苯二膦配体的非对映选择性合成及其在不对称氢化中的应用
7. Biheteroaromatic diphosphines and their transition metal complexes : synthesis, characterisation and applications in asymmetric catalysis [O] . Au-Yeung TTL, Chan ASC 2004

机译：双杂芳族二膦及其过渡金属配合物的合成，表征及在不对称催化中的应用

Biheteroaromatic diphosphines and their transition metal complexes: synthesis, characterisation and applications in asymmetric catalysis

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