The effects of electronic coupling and solvent broadening on the intervalent electron transfer of a centrosymmetric mixed-valence complex

David f. Watson; Andrew B. Bocarsly

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The effects of electronic coupling and solvent broadening on the intervalent electron transfer of a centrosymmetric mixed-valence complex

机译：电子耦合和溶剂增宽对中心对称混合价配合物的间歇电子转移的影响

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A three-dimensional nuclear coordinate representation of the intervalent electron transfer processes occurring in the trinuclear mixed-valence complex, [(NC)_5Fe(II)-CN- Pt(IV)(NH_3)_4-NC-e(II)(CN)_5]~4-, is discussed in terms of the degree of coupling between Electronic states. The related dinuclear complex, (NC)_5Fe(II)-CN-Pt(IV)-NH_3)_5, has been Synthesized and characterized by UV-VIS and IR absorption spectroscopies, cyclic voltam- Metry, resonance Raman spectroscopy, and single crystal X-ray diffraction.

机译：三核混合价络合物[（NC）_5Fe（II）-CN- Pt（IV）（NH_3）_4-NC-e（II）（CN）中发生的间歇性电子转移过程的三维核坐标表示）_5]〜4-，根据电子状态之间的耦合程度进行讨论。相关的双核络合物（NC）_5Fe（II）-CN-Pt（IV）-NH_3）_5已通过UV-VIS和IR吸收光谱，循环伏安法，共振拉曼光谱和单晶合成并表征X射线衍射。

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《Coordination chemistry reviews》 |2001年第2001期|p.177-194|共18页
作者
David f. Watson; Andrew B. Bocarsly;
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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Electronic coupling; Solvent broadening; Mixed-valence complex;

机译：电子耦合;溶剂增宽;混合价复合物;

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1. Structure and electronic properties of biferrocene-TCNQ charge-transfer complexes:Effects of acceptors and crystal environment on the mixed-valence states [J] . Tomoyuki Mochida, Shizue Yamazaki, Shinya Suzuki, Bulletin of the Chemical Society of Japan . 2003,第12期

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2. Orbital Specific Charge Transfer Distances, Solvent Reorganization Energies, and Electronic Coupling Energies: Electronic Stark Effect Studies of Parallel and Orthogonal Intervalence Transfer in (NC)_5Os~ Ⅱ-CN-Ru~Ⅲ(NH_3)_5~- [J] . Laba Karki, Joseph T. Hupp Journal of the American Chemical Society . 1997,第17期

机译：轨道比电荷转移距离，溶剂重组能和电子耦合能：（NC）_5Os〜Ⅱ-CN-Ru〜Ⅲ（NH_3）_5〜-中平行和正交间隔转移的电子斯塔克效应研究
3. An ab initio study of specific solvent effects on the electronic coupling element in electron transfer reactions [J] . Henderson TM., Cave RJ. The Journal of Chemical Physics . 1998,第17期

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6. Polymorphism in the 1:1 Charge-Transfer Complex DBTTF-TCNQ and Its Effects on Optical and Electronic Properties [O] . Dr. Katelyn P. Goetz, Dr. Jun’ya Tsutsumi, Dr. Sujitra Pookpanratana, -1

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7. An Ab Initio Study of Specific Solvent Effects on the Electronic Coupling Element in Electron Transfer Reactions [O] . Henderson, Thomas M., u2798, Cave, Robert J. 1998

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8. Solvent Dynamical Effects in Electron Transfer: Evaluation of Electronic Matrix Coupling Elements for Metallocene Self-Exchange Reactions [R] . McManis, G. E., Nielson, R. M., Gochev, A., 1989

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The effects of electronic coupling and solvent broadening on the intervalent electron transfer of a centrosymmetric mixed-valence complex

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