MLCT excited states of cupprous bis-phenanthroline coordination compounds

Donald V. Scaltritio; David W. Thompson; John A. OCallaghan

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MLCT excited states of cupprous bis-phenanthroline coordination compounds

机译：MLCT铜双邻菲咯啉配位化合物的激发态

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Cuprous bis-phenanthroline compounds possess metal-to-ligand charge transfer, MLCT, excited states. Phenanthrolien lgiands corrdinated to Cu(I) that are disubstituted in the 2- and 9-positions with alkyl or aryl groups, abbrevaited Cu~I(phen')~+_2, have long-lived excited states at room temperature. The parent Cu~I(phen)~+_2 compound is non-emissive under the same conditions with a short excited state lifetime, τ<10 ns.

机译：铜双菲咯啉化合物具有金属到配体的电荷转移，MLCT和激发态。与Cu（I）配位的菲在2和9位被烷基或芳基双取代，简称Cu〜I（phen'）〜+ _2，在室温下具有长寿命的激发态。母体Cu〜I（phen）〜+ _2化合物在相同条件下具有非发射性，且激发态寿命短，τ<10 ns。

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来源
《Coordination chemistry reviews》 |2000年第2000期|p.243-266|共24页
作者
Donald V. Scaltritio; David W. Thompson; John A. OCallaghan;
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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Copper; MLCT excited states; Exciplex;

机译：铜;MLCT激发态;复杂;

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2. The importance of the 3MLCT excited state of Ru(II), Re(I) and Ir(III) compounds on development of photosensors, oleds and CO2 photoreduction [J] . Müller Andressa V., Gon?alves Márcia R., Ramos Luiz D., Quimica nova . 2017,第2期

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4. Intramolecular energy transfer and excitation coupling in metal-to-ligand charge transfer (MLCT) excited states [C] . Hans Riesen, Australian National Univ., Canberra, International Conference on Excitonic Processes in Condensed Matter . 1995

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5. Excited State Manipulations in Mo(II) Dimers and Re(I) MLCT Complexes [D] . Joyce, Rosalynd Ruby-Michelle 2018

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MLCT excited states of cupprous bis-phenanthroline coordination compounds

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