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Progress of nanostructured metal oxides derived from metal-organic frameworks as anode materials for lithium-ion batteries

机译：纳米结构金属氧化物衍生自金属有机框架的进展作为锂离子电池的阳极材料

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摘要

Metal-organic frameworks (MOFs) are the newly crystalline porous materials with outstanding structural, compositional, and morphological features, which have garnered much attention in all dimensions of major scientific and engineering fields, including energy storage and conversion. Various pristine MOFs and their derivatives have been developed and used as anode materials in lithium-ion batteries (LIBs). In this review, we specifically focused on MOFs-derived nanostructured metal oxides with diverse structural and compositional features that exhibit exceptional lithium storage capacity. These intriguing nanostructures inherit the multidimensional structure of MOF and the advantage of even distribution of metallic species after thermal decomposition, which facilitates fast reaction kinetics of lithium transportation and ultimately improves the battery performance. Herein, we review and categorise the synthetic strategies to achieve various transitional metal oxide nanostructures/composites obtained from BDC/BTC-based MOFs (H2BDC = 1,4-benzenedicarboxylic acid, H3BTC = 1,3,5-benzenetricarboxylic acid), zeolitic imidazolate frameworks (ZIFs), Prussian blue and Prussian blue analogues (PB and FBAs), and other unusual porous crystalline MOF materials. In addition, we will also compare the electrochemical performances of various metal oxides (MOs) nanostructures obtained via heteroatom doping in the pristine MOF precursor or by tuning their structure. Finally, our discussion will focus on the advantages and future developments in design and fabrication of new MOF-derived metal oxide electrode materials with high energy efficiencies in relation with the next generation rechargeable battery applications. (C) 2020 Elsevier B.V. All rights reserved.
机译：金属有机框架（MOFS）是新的结晶多孔材料，具有出色的结构，组成和形态特征，这在主要科学和工程领域的所有维度中都有很大的关注，包括能量存储和转换。已经开发了各种原始MOF和它们的衍生物并用作锂离子电池（LIBS）中的阳极材料。在本次综述中，我们专注于MOFS衍生的纳米结构金属氧化物，具有不同的结构和组成特征，具有出色的锂储存能力。这些有趣的纳米结构继承了MOF的多维结构和热分解后金属物种的均匀分布的优点，这有利于锂运输的快速反应动力学，并最终提高电池性能。在此，我们审查和分类合成策略以实现从BDC / BTC基MOF获得的各种过渡金属氧化物纳米结构/复合材料（H2BDC = 1,4-苯并二羧酸，H3BTC = 1,3,5-苯甲酸），沸石咪唑酯框架（ZIFS），普鲁士蓝和普​​鲁士蓝色类似物（PB和FBA）和其他不寻常的多孔晶体MOF材料。此外，我们还将比较通过掺杂在原始MOF前体中的杂原子掺杂的各种金属氧化物（MOS）纳米结构的电化学性能或通过调节它们的结构。最后，我们的讨论将侧重于设计和制造新的Mof衍生的金属氧化物电极材料的优缺点，具有高能量效率与下一代可再充电电池应用。 （c）2020 Elsevier B.v.保留所有权利。

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  • 来源
    《Coordination chemistry reviews》 |2020年第10期|213434.1-213434.21|共21页
  • 作者

    Reddy R. Chenna Krishna; Lin Jia; Chen Yueying; Zeng Chenghui; Lin Xiaoming; Cai Yuepeng; Su Cheng-Yong;

  • 作者单位

    South China Normal Univ Guangzhou Key Lab Mat Energy Convers & Storage Key Lab Theoret Chem Environm Minist Educ Sch Chem Guangzhou 510006 Peoples R China|Jiangxi Normal Univ Coll Chem & Chem Engn Key Lab Funct Small Organ Mol Minist Educ Nanchang 330022 Jiangxi Peoples R China|Jiangxi Normal Univ Jiangxis Key Lab Green Chem Nanchang 330022 Jiangxi Peoples R China;

    South China Normal Univ Guangzhou Key Lab Mat Energy Convers & Storage Key Lab Theoret Chem Environm Minist Educ Sch Chem Guangzhou 510006 Peoples R China;

    South China Normal Univ Guangzhou Key Lab Mat Energy Convers & Storage Key Lab Theoret Chem Environm Minist Educ Sch Chem Guangzhou 510006 Peoples R China;

    Jiangxi Normal Univ Coll Chem & Chem Engn Key Lab Funct Small Organ Mol Minist Educ Nanchang 330022 Jiangxi Peoples R China|Jiangxi Normal Univ Jiangxis Key Lab Green Chem Nanchang 330022 Jiangxi Peoples R China;

    South China Normal Univ Guangzhou Key Lab Mat Energy Convers & Storage Key Lab Theoret Chem Environm Minist Educ Sch Chem Guangzhou 510006 Peoples R China|South China Univ Technol Sch Environm & Energy Guangzhou 510006 Peoples R China;

    South China Normal Univ Guangzhou Key Lab Mat Energy Convers & Storage Key Lab Theoret Chem Environm Minist Educ Sch Chem Guangzhou 510006 Peoples R China;

    Sun Yat Sen Univ MOE Lab Bioinorgan & Synthet Chem Lehn Inst Funct Mat Sch Chem Guangzhou 510275 Peoples R China;

  • 收录信息 美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Metal-organic frameworks; Metal oxides; Anodes; Lithium-ion batteries;

    机译：金属有机框架;金属氧化物;阳极;锂离子电池;

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