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Exchange reactions in metal-organic frameworks: New advances

机译：金属有机框架中的交换反应：新进展

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There has been considerable interest and importance in using the "exchange reaction" to synthesize, modify, or functionalize metal-organic frameworks (MOFs), since the "exchange" can achieve desired changes in their structures and performances for various applications. In 2014, we published a critical review on this topic, in which the exchange of metal ions, ligands, and guests was discussed in detail. In the past five years, much progress has been made and some new and important results were published, which significantly promoted the development of MOF chemistry. In this review, the exchange reactions of the two main components of MOFs, namely metal center ions and ligands, are summarized based on the new results since 2014. The influence factors and processes of the exchange reactions are firstly discussed for guiding the design of functional MOFs. The lately reported works on exchange reactions of MOFs classified into two groups with seven subgroups are then introduced. Finally, a perspective is given, expecting that the exchange reactions will play a more and more important role in exploring novel or functional MOFs for applications in the future. (C) 2020 Elsevier B.V. All rights reserved.
机译：利用“交换反应”在合成，修改或官能化金属有机框架（MOFS）中存在相当大的兴趣和重要性，因为“交换”可以达到其结构和各种应用的性能的所需变化。 2014年，我们在这一主题发表了一个关键审查，其中详细讨论了金属离子，配体和客人的交换。在过去的五年中，已经提出了很大的进展，并发表了一些新的和重要成果，这显着促进了MOF化学的发展。在本文中，根据2014年以来的新结果，总结了MOF，即金属中心离子和配体的两个主要成分的交换反应。首先讨论了换取反应的影响因素和过程，以指导功能的设计MOF。然后介绍了最近报道的作品，用于将MOF的交换反应分为七个亚组的两组。最后，给出了一种观点，期望交换反应将在探索未来应用的新颖或功能MOF方面发挥越来越重要的作用。 （c）2020 Elsevier B.v.保留所有权利。

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