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首页> 外文期刊>Coordination chemistry reviews >An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application
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An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application

机译：Actinide金属 - 有机框架（AN-MOFS）的更新状态和趋势：从合成到应用

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摘要

Actinide metal-organic frameworks (An-MOFs) consisting of actinide nodes and organic linkers represent an underexplored category of coordination polymers due to challenges in their synthesis and characterization. The unparalleled coordination chemistry of actinide elements confers a huge opportunity to explore the rational design, chemical reactivity, and versatile properties of An-MOFs as one of the most intriguing class of metal-organic frameworks (MOFs). Significant advances in this "juvenile" MOF research field have been witnessed in recent years and progress in the An-MOFs area since 2003 has been reviewed from the aspects of the synthesis, structure, and applications. The preparative handling and synthetic strategies implemented in constructing An-MOFs are illustrated. Their structure motifs are then classified and expounded by actinide building blocks and organic linkers. The modularity, topology, and porosity of An-MOFs are specified to highlight a great potential to tune their electronic structures and ensuing properties. Ultimately, applications of An-MOFs as selective adsorbents, heterogenous catalysts, luminescent sensors, conducting, and semiconducting materials, and nuclear targets are underlined. This updated review is envisaged to guide in-depth investigation of largely elusive transuranium MOFs and the development of thorium or uranium-based MOFs towards practical applications. (C) 2021 Elsevier B.V. All rights reserved.
机译：由活性节点和有机接头组成的Actinide金属 - 有机框架（AN-MOF）代表了由于其合成和表征的挑战，其缺乏缺陷的配位聚合物类别。非恒星元素的无与伦比的协调化学赋予了一个巨大的机会，探讨了AN-MOF的合理设计，化学反应性和多功能性能作为金属有机骨架（MOFS）中最有趣的类别之一。近年来，这一“少年”MOF研究领域的重大进展并于2003年以来，从合成，结构和应用方面进行了审查自2003年以来的进展。说明了在构建AN-MOF中实施的制备性处理和合成策略。然后，它们的结构图案被Actinide构建块和有机接头分类和阐述。指定了AN-MOF的模块化，拓扑和孔隙率，以突出显示它们的电子结构和随后的特性的巨大潜力。最终，将AN-MOF作为选择性吸附剂，异源催化剂，发光传感器，导电和半导体材料的应用。预计此更新的审查是为了指导深入调查基本难以捉摸的经过铀MOF和钍或铀的MOF对实际应用的开发。 （c）2021 elestvier b.v.保留所有权利。

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  • 来源
    《Coordination chemistry reviews》 |2021年第11期|214011.1-214011.81|共81页
  • 作者

    Lv Kai; Fichter Sebastian; Gu Mei; Marz Juliane; Schmidt Moritz;

  • 作者单位

    China Acad Engn Phys Inst Nucl Phys & Chem Radiochem Lab Mianyang 621900 Sichuan Peoples R China|Helmholtz Zentrum Dresden Rossendorf HZDR Inst Resource Ecol Bautzner Landstr 400 D-01328 Dresden Germany;

    Helmholtz Zentrum Dresden Rossendorf HZDR Inst Resource Ecol Bautzner Landstr 400 D-01328 Dresden Germany;

    China Acad Engn Phys Inst Nucl Phys & Chem Radiochem Lab Mianyang 621900 Sichuan Peoples R China;

    Helmholtz Zentrum Dresden Rossendorf HZDR Inst Resource Ecol Bautzner Landstr 400 D-01328 Dresden Germany;

    Helmholtz Zentrum Dresden Rossendorf HZDR Inst Resource Ecol Bautzner Landstr 400 D-01328 Dresden Germany;

  • 收录信息 美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Actinide coordination chemistry; Metal-organic frameworks; Actinide MOF; Transuranium elements; Uranium and thorium; Properties and applications;

    机译：神光协调化学;金属有机框架;Actinide MOF;过铀元素;铀和钍;性质和应用;

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