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首页> 外文期刊>Corrosion science >Insight into the acceleration in oxidation kinetics ahead of stress corrosion crack of alloy 690 in simulated PWR primary water
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Insight into the acceleration in oxidation kinetics ahead of stress corrosion crack of alloy 690 in simulated PWR primary water

机译:在模拟PWWR初级水中洞察合金690的应力腐蚀裂纹之前的氧化动力学的加速度

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摘要

The acceleration in oxidation kinetics beyond a stress corrosion crack of alloy 690 in simulated PWR primary water was clarified by comparing the oxide depths at two identical carbide/matrix interfaces along a single grain boundary. Compact chromia layer formed along these two interfaces at vastly different rates. Stress concentration ahead of the crack tip only slightly increased the oxidation rate as the crack is still very shallow. Deformation localization near the crack plays a dominant role in accelerating oxidation kinetics as the associated high vacancy concentration can promote the diffusivity of oxygen by over an order of magnitude.
机译:通过将沿着单晶边界的两个相同的碳化物/基质界面比较氧化物深度,澄清了氧化动力学的加速度超出了模拟PR初级水的应力腐蚀裂纹。紧凑型铬层沿着这两个界面形成,以极大的速率。由于裂缝仍然非常浅,因此裂缝尖端的应力集中仅略微增加氧化率。随着相关的高空位浓度可以通过超过一个数量级促进氧的扩散性,在加速氧化动力学附近的变形定位在加速氧化动力学中起着显着作用。

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  • 来源
    《Corrosion science》 |2020年第11期|108943.1-108943.10|共10页
  • 作者单位

    Xi An Jiao Tong Univ Ctr Adv Mat Performance Nanoscale CAMP Nano State Key Lab Mech Behav Mat Xian 710049 Peoples R China;

    Univ Michigan Dept Nucl Engn & Radiol Sci Ann Arbor MI 48109 USA;

    Xi An Jiao Tong Univ Ctr Adv Mat Performance Nanoscale CAMP Nano State Key Lab Mech Behav Mat Xian 710049 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Alloy; STEM; Oxidation; Interfaces; Kinetic parameters; Stress corrosion;

    机译:合金;茎;氧化;界面;动力学参数;压力腐蚀;

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