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Selective dissolution of amorphous and nanocrystalline Zr_2Ni

机译:非晶态和纳米晶Zr_2Ni的选择性溶解

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摘要

Rapidly quenched Zr_2Ni amorphous and nanocrystalline ribbons were subjected to electrochemical selective dissolution. The porous structure of the dealloyed materials showed a dependence on the alloy microstructure. The etching takes place with constant rate in three dimensions, indicating a surface controlled dissolution process. The etching rate of the amorphous alloy was found to be lower than for the nanocrystalline material. Partial crystallization of the de-alloyed amorphous ribbon has been observed. The electrocatalytic activity for Hydrogen evolution reaction of the selectively dissolved amorphous and nanocrystalline ribbons was found to be improved compared to the as-cast alloys.
机译:快速淬火的Zr_2Ni非晶态和纳米晶带进行电化学选择性溶解。脱合金材料的多孔结构显示出对合金微观结构的依赖性。蚀刻在三个维度上以恒定速率进行,这表明表面受控的溶解过程。发现非晶态合金的蚀刻速率低于纳米晶材料的蚀刻速率。已经观察到脱合金的非晶带的部分结晶。发现与铸态合金相比,选择性溶解的非晶态和纳米晶带的氢析出反应的电催化活性得到改善。

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  • 来源
    《Corrosion science》 |2013年第9期|308-313|共6页
  • 作者单位

    Faculty of Chemistry and Pharmacy, University of Sofia 'St. Kl. Ohridski', I James Bourchier Sir., 1164 Sofia, Bulgaria;

    Faculty of Chemistry and Pharmacy, University of Sofia 'St. Kl. Ohridski', I James Bourchier Sir., 1164 Sofia, Bulgaria;

    Faculty of Chemistry and Pharmacy, University of Sofia 'St. Kl. Ohridski', I James Bourchier Sir., 1164 Sofia, Bulgaria;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Alloy; Zr-Ni glass; Cyclic voitammetry; Polarization; de-alloying;

    机译:合金;锆镍玻璃;循环测空法;偏振;脱合金;

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