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首页> 外文期刊>BioTechnology: An Indian Journal >The influence of temperature on the ECL behavior of the benzhexol hydrochloride -Ru(bpy)32+ system ongraphite electrode
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The influence of temperature on the ECL behavior of the benzhexol hydrochloride -Ru(bpy)32+ system ongraphite electrode

机译：温度对盐酸苄索尔-Ru（bpy）32+体系石墨电极的ECL行为的影响

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摘要

The influence of temperature on the electrochemiluminescence (ECL) behavior of the benzhexol hydrochloride -Ru(bpy)3 2+ system was studied by means of electrochemistry, chemiluminescence and fluorescence on graphite electrode. The results showed that the temperature has a significant impact on the ECL behavior of the benzhexol hydrochloride - Ru(bpy)3 2+ system from 0?????¨ to 70?????¨, the current intensity was enhanced with the increase of temperature, and the chemiluminescence intensity of the benzhexol hydrochloride-Ru(bpy)3 2+ system increased from 0?????¨ to 30?????¨ and then decreased. Under the optimum conditions, the linear range for benzhexol hydrochloride from 1×10-8-1×10- 4mol?L-1 and the detection limit (S/N=3) of 6.0×10-9 mol?L-1 were obtained, and the satisfactory reproducibility, relative errors and recoveries were gained. These results indicated that the testing temperature had an significant influence on the ECL behavior of the Ru(bpy)3 2+ system.
机译：通过电化学，化学发光和石墨电极上的荧光研究了温度对盐酸苯卓克索-Ru（bpy）3 2+体系电化学发光（ECL）行为的影响。结果表明，温度从0℃〜70℃至70℃对苯扎洛尔Ru（bpy）3 2+体系的ECL行为有显着影响，电流强度随温度的升高而增强。随着温度的升高，盐酸苄索尔-Ru（bpy）3 2+体系的化学发光强度从0℃升高到30℃，然后降低。在最佳条件下，盐酸苯卓克索的线性范围为1×10-8-1×10-4mol·L-1，检出限（S / N = 3）为6.0×10-9mol·L-1。获得了令人满意的重现性，相对误差和回收率。这些结果表明，测试温度对Ru（bpy）3 2+系统的ECL行为有重大影响。

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