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首页> 外文期刊>Brazilian journal of chemical engineering >EVALUATION OF DISTILLATION CURVES FOR BIO-OIL OBTAINED FROM THERMAL CRACKING OF WASTE COOKING OIL
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EVALUATION OF DISTILLATION CURVES FOR BIO-OIL OBTAINED FROM THERMAL CRACKING OF WASTE COOKING OIL

机译:废蒸煮油热裂解获得的生物油蒸馏曲线的评估

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摘要

Bio-oil obtained from thermal cracking of waste cooking oil (WCO) is a complex mixture of different chemical compounds and, like crude oil, it is composed mainly of hydrocarbons. The large number of compounds in bio-oil leads to complex and expensive methods for its properties determination. In this study, the distillation curves were constructed for samples of bio-oils obtained from the thermal cracking of WCO in order to predict the properties (such as molecular weight, viscosity and refractive index). Although it is not often employed for bio-oil analyses, the distillation curve method is commonly used in the petroleum industry. Atmospheric and vacuum distillations were performed according to ASTM D86 and ASTM D1160 standards, respectively, for six samples of bio-oil and one sample of crude oil. The results were converted to true boiling point (ASTM D2892) according to the API method (1997) and common petroleum refining correlations were employed. The estimated values for the properties showed little deviation in relation to the experimental data. The bio-oil and crude oil samples contained heavy compounds in their composition, and all samples studied are considered as heavy oils considering the °API range.
机译:从废烹饪油(WCO)进行热裂解获得的生物油是不同化学化合物的复杂混合物,并且像原油一样,它主要由碳氢化合物组成。生物油中大量的化合物导致了复杂而昂贵的测定其性能的方法。在这项研究中,为从WCO的热裂解获得的生物油样品绘制了蒸馏曲线,以预测其性能(例如分子量,粘度和折射率)。尽管通常不用于生物油分析,但蒸馏曲线法通常用于石油工业。分别根据ASTM D86和ASTM D1160标准进行了常压蒸馏和真空蒸馏,分别对6个生物油样品和1个原油样品进行了蒸馏。根据API方法(1997年)将结果转换为真实沸点(ASTM D2892),并采用常见的石油精炼相关性。性能的估计值相对于实验数据显示出很小的偏差。生物油和原油样品的成分中含有重化合物,考虑到API范围,所有研究的样品均被视为重油。

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