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首页> 外文期刊>Bulletin of Japan Society of Coordination Chemistry >Creation of Electro- and Photo-functional Molecular Systems Based on Coordination Programming
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Creation of Electro- and Photo-functional Molecular Systems Based on Coordination Programming

机译：基于协调编程的电光功能分子系统的创建

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In this review, a new research area on highly integrated metal-containing p-conjugated and/or redox-active systems constructed by coordination programming , which is to utilize the advantages of coordination chemistry to control the chemical bonds and arrangements of metal atoms and ions for creation of superstructures, has been reported. The topics involved are 1) interfacial synthesis of p-conjugated redox complex oligomer/polymer wires on electrodes and analysis of their electron conduction mechanism and kinetics, 2) creation of coordination nanosheets (CONASHs), 3) synthesis of p-conjugated redox metal complex oligomers, polymers and clusters and analysis of their electronic properties, 4) synthesis of metal complexes responsive to external-stimuli and analysis of their unique properties and functions, 5) metal nanoparticles coordinated with functional molecules, and 6) development of bio-photosensors using combination of cyanobacterial photosystem I and molecular wire. These research results indicate that coordination programming is a promising approach to construct intelligent hetero-molecular conjugated systems useful for development of chemical devices.
机译：在这篇综述中，通过配位程序构建了一个高度集成的含金属的p-共轭和/或氧化还原活性系统的新研究领域，该领域将利用配位化学的优势来控制金属的化学键和排列已经报道了用于产生超结构的原子和离子。涉及的主题是1）电极上p共轭氧化还原络合物低聚物/聚合物线的界面合成及其电子传导机理和动力学分析; 2）配位纳米片（CONASH）的创建; 3）p共轭氧化还原金属络合物的合成低聚物，聚合物和团簇及其电子性质分析; 4）响应外部刺激的金属配合物的合成及其独特性质和功能的分析; 5）与功能分子配合的金属纳米粒子; 6）使用生物光传感器的开发蓝细菌光系统I和分子线的组合。这些研究结果表明，配位编程是构建可用于化学装置开发的智能杂分子共轭系统的有前途的方法。

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