Glass fiber supports modified by layers of silica and carbon nanofibers

Maxim V. Popov; Sergey V. Zazhigalov; Tatyana V. Larina; Svetlana V. Cherepanova; Alexander G. Bannov; Sergey A. Lopatin; Andrey N. Zagoruiko

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Glass fiber supports modified by layers of silica and carbon nanofibers

机译：玻璃纤维载体经过二氧化硅和碳纳米纤维层的改性

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The new multi-layered composite was manufactured by deposition of the carbon nanofibers (CNF) at the surface of the glass-fiber fabric, which is pre-modified by application of additional external layers of NiO and porous silica. Carbonization of synthesized catalytic template was performed at 450 °C in propanebutane media at ambient pressure. CNF was deposited in amount of ~130% of initial template mass or 65 g per g of nickel, the specific surface area of the material is ~100 m2/g. The synthesized material has high mechanical strength, high hydrophobicity and strong bonding between CNF and glass-fiber support. The synthesis method is technologically simple, inexpensive and easily scalable. It is possible to manufacture such material in various solid shapes, using the flexibility of the primary glass-fiber support; in particular, it may be used for production of the mechanically self-sustainable catalytic cartridges with required shape and internal geometry using no additional structuring elements.

机译：通过在玻璃纤维织物的表面沉积碳纳米纤维（CNF）来制造新的多层复合材料，该碳纳米纤维通过施加额外的NiO和多孔二氧化硅外层进行了预改性。合成的催化模板的碳化在室温下于丙烷丁烷介质中于450°C进行。 CNF的沉积量约为初始模板质量的130％或每克镍65克，材料的比表面积约为100平方米/克。合成材料具有高机械强度，高疏水性以及CNF与玻璃纤维载体之间的牢固结合。该合成方法技术上简单，便宜且易于扩展。利用初级玻璃纤维支架的柔韧性，可以将这种材料制成各种实心形状。特别是，它可以用于生产具有所需形状和内部几何形状的机械自持式催化器，而无需使用其他结构元件。

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《Catalysis for Sustainable Energy》 |2017年第1期|共6页
作者
Maxim V. Popov; Sergey V. Zazhigalov; Tatyana V. Larina; Svetlana V. Cherepanova; Alexander G. Bannov; Sergey A. Lopatin; Andrey N. Zagoruiko;
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中图分类物理化学（理论化学）、化学物理学;
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1. Preparation and characterization of aluminosilicate supports with a synthesized layer of catalytic filamentous carbon: I. Synthesis of carbon nanofibers on a supported nickel catalyst [J] . Kovalenko GA, Komova OV, Chuenko TV, Kinetics and catalysis . 2007,第5期

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机译：具有催化丝状碳合成层的硅铝酸盐载体的制备和表征：II。负载钴催化剂上碳纳米纤维的合成
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机译：疲劳载荷对开孔碳纳米纤维改性玻璃纤维/环氧复合材料中电阻抗的影响
5. Interlaminar fracture toughness and fatigue delamination of carbon nanofibers modified polyester/ glass fiber laminates. [D] . Farah, Basil I. 2012

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6. Direct Electron Transfer of Hemoglobin on Manganese III Oxide-Ag Nanofibers Modified Glassy Carbon Electrode [O] . Masoud Negahdary, Gholamreza Mazaheri, Somyyeh Rad, 2009

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7. Glass fiber supports modified by layers of silica and carbon nanofibers [O] . Popov Maxim V., Zazhigalov Sergey V., Larina Tatyana V., 2017

机译：由二氧化硅和碳纳米纤维层改性的玻璃纤维载体

Glass fiber supports modified by layers of silica and carbon nanofibers

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