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Catalytic quality improvement of waste polyolefin originated fractions

机译:废聚烯烃衍生馏分的催化质量改进

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摘要

The demand for alternative fuels having low greenhouse gases emission is continuously growing worldwide. Therefore it is preferred to produce new, waste originated components. One option is the recycling of plastic waste with cracking. The produced hydrocarbon fraction is not suitable for fuels thus it is important to improve its quality. The aim of our experimental work was to study the quality improvement of this cracked fraction (PPCGO) and crude oil based middle distillates (different composition) with co-processing. Our goal was to produce high quality diesel fuel blending components. We studied the effect of process parameters on the quality of products. Ni (2.3%) Mo (11.0%) P (2.3%)/Al2O3 catalyst was used. During the experiments we studied the hydrogenation of olefins, saturation of aromatics and desulphurization. The hydrogenation of olefins was practically complete at 300°C. It took place at significantly higher speed than the desulphurization reactions. In case of light gas oil feedstock the products had significantly lower sulphur contents; below 10 mg/kg already at 340°C. We determined that the cracked fraction had beneficial effect on the performance properties of the products. In case of all feedstock combinations, we found process parameters which can be used to produce high-quality diesel fuel blending components on the tested catalyst.
机译:全球对低温室气体排放的代用燃料的需求在不断增长。因此,最好生产新的,废料来源的部件。一种选择是回收带有裂化的塑料废料。产生的烃馏分不适合用作燃料,因此提高其质量很重要。我们实验工作的目的是研究通过共处理提高裂解级分(PPCGO)和基于原油的中间馏分(不同组成)的质量。我们的目标是生产高质量的柴油调和组分。我们研究了工艺参数对产品质量的影响。使用了Ni(2.3%)Mo(11.0%)P(2.3%)/ Al2O3催化剂。在实验过程中,我们研究了烯烃的氢化,芳烃的饱和和脱硫。烯烃的氢化实际上在300℃下完成。它以比脱硫反应高得多的速度发生。在轻瓦斯油原料的情况下,产品的硫含量明显降低;在340°C时已低于10 mg / kg。我们确定裂化级分对产品的性能具有有益的影响。在所有原料组合的情况下,我们发现了可用于在测试的催化剂上生产高质量柴油混合组分的工艺参数。

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